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Palladium catalyzed cycloisomerization of 1,6-enynes

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Authors
오혜미
Advisor
정영근
Major
자연과학대학 화학부
Issue Date
2013-02
Publisher
서울대학교 대학원
Description
학위논문 (석사)-- 서울대학교 대학원 : 화학부 무기화학 전공, 2013. 2. 정영근.
Abstract
A palladium-catalyzed cycloisomerization of 1,6-enynes, which can provide a variety of cyclic compounds, has been studied, The reaction pathway is highly dependent upon a leaving group of 1,6-enynes. Enynes with a phosphate leaving group gave rise to 5.7-bicyclic trienes and by an alkoxy group yielded monocyclic trienes. We also observed a Pd(∏)-catalyzed cycloisomerizaiotn of 1,6-enynes to bicyclo[4.1.0]heptenes in good yields under optimized conditions.
Language
English
URI
http://hdl.handle.net/10371/134885
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College of Humanities (인문대학)Korean Language and Literature (국어국문학과)Others_국어국문학과
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