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Oxidant-free, Iron-catalyzed Acceptorless Alcohol Dehydrogenation

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Authors
송한수
Advisor
Soon Hyeok Hong
Major
자연과학대학 화학부
Issue Date
2014-08
Publisher
서울대학교 대학원
Keywords
철촉매
Description
학위논문 (석사)-- 서울대학교 대학원 : 화학부, 2014. 8. 홍순혁.
Abstract
Oxidation of alcohols is an essential organic reaction, affording versatile carbonyl groups. To provide a sustainable solution for environmentally harmful traditional oxidation methods, the transition-metal catalyzed oxidant-free dehydrogenation of alcohols has attracted much attention. The widely used catalysts for the dehydrogenation reaction are based on precious metals, which are not economical and environmentally benign catalysts. We developed an operationally simple, economical, and environmentally benign acceptorless Fe-catalyzed dehydrogenation of various secondary benzylic alcohols to afford the corresponding ketones and H2. A simple in-situ mixture of readily available Fe(III) acetylacetonate, 1,10-phenanthroline, and K2CO3 was identified as an active catalyst for this transformation.
Language
Korean
URI
http://hdl.handle.net/10371/134911
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College of Humanities (인문대학)Korean Language and Literature (국어국문학과)Others_국어국문학과
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