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Light-Induced pH-Responsive Degradation of Fumaramic Acid Derivatives

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Authors
최원민
Advisor
이연
Major
자연과학대학 화학부
Issue Date
2015-02
Publisher
서울대학교 대학원
Keywords
photoisomerizationpH-sensitivitysignal-responsivenesstandem reactionselectivityphotochemical reaction
Description
학위논문 (석사)-- 서울대학교 대학원 : 화학부, 2015. 2. 이연.
Abstract
. Fumaramic acid derivatives can be converted into their cis-isomer maleamic acid derivatives under UV illumination, and these maleamic acid derivatives show pH-responsive degradability at acidic pH only after the preceding photoisomerization. The rate of the tandem photoisomerization-degradation of fumaramic acid derivatives can be finely controlled by changing the substituents on the double bond. Photoisomerization-based unlocking of the pH-responsive degradability of fumaramic acid derivatives has strong potential for the development of multi-signal-responsive smart materials in biomedical applications.
Language
English
URI
http://hdl.handle.net/10371/134916
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College of Humanities (인문대학)Korean Language and Literature (국어국문학과)Others_국어국문학과
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