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Involvement of high-valent manganese-oxo intermediates in oxidation reactions: realisation in nature, nano and molecular systems
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Balamurugan, Mani | - |
dc.contributor.author | Saravanan, Natarajan | - |
dc.contributor.author | Ha, Heonjin | - |
dc.contributor.author | Lee, Yoon Ho | - |
dc.contributor.author | Nam, Ki Tae | - |
dc.date.accessioned | 2018-10-05T01:55:34Z | - |
dc.date.available | 2018-10-05T10:57:06Z | - |
dc.date.issued | 2018-07-04 | - |
dc.identifier.citation | Nano Convergence, 5(1):18 | ko_KR |
dc.identifier.issn | 2196-5404 | - |
dc.identifier.uri | https://hdl.handle.net/10371/142840 | - |
dc.description.abstract | Abstract
Manganese plays multiple role in many biological redox reactions in which it exists in different oxidation states from Mn(II) to Mn(IV). Among them the high-valent manganese-oxo intermediate plays important role in the activity of certain enzymes and lessons from the natural system provide inspiration for new developments of artificial systems for a sustainable energy supply and various organic conversions. This review describes recent advances and key lessons learned from the nature on high-valent Mn-oxo intermediates. Also we focus on the elemental science developed from the natural system, how the novel strategies are realised in nano particles and molecular sites at heterogeneous and homogeneous reaction conditions respectively. Finally, perspectives on the utilisation of the high-valent manganese-oxo species towards other organic reactions are proposed. | ko_KR |
dc.description.sponsorship | This review was supported by Basic Science Research Program (2017R1A2B3012003) which is funded by the National Research Foundation (NRF) under the Ministry of Science, ICT and Future Planning (MSIP), South Korea and the KIST Institutional Program (2V06170). | ko_KR |
dc.language.iso | en | ko_KR |
dc.publisher | Springer Open | ko_KR |
dc.subject | High-valent | ko_KR |
dc.subject | Mn-oxo | ko_KR |
dc.subject | OEC | ko_KR |
dc.subject | RNR | ko_KR |
dc.subject | Biomimetic | ko_KR |
dc.title | Involvement of high-valent manganese-oxo intermediates in oxidation reactions: realisation in nature, nano and molecular systems | ko_KR |
dc.type | Article | ko_KR |
dc.contributor.AlternativeAuthor | 하헌진 | - |
dc.contributor.AlternativeAuthor | 이윤호 | - |
dc.contributor.AlternativeAuthor | 남기태 | - |
dc.identifier.doi | 10.1186/s40580-018-0150-5 | - |
dc.language.rfc3066 | en | - |
dc.rights.holder | The Author(s) | - |
dc.date.updated | 2018-07-08T03:50:23Z | - |
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