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A gel polymer electrolyte based on initiator-free photopolymerization for lithium secondary batteries

Cited 56 time in Web of Science Cited 55 time in Scopus
Authors
Ryou, Myung-Hyun; Lee, Yong Min; Cho, Kuk Young; Han, Gi-Beom; Lee, Je-Nam; Lee, Dong Jin; Choi, Jang Wook; Park, Jung-Ki
Issue Date
2012-01
Citation
Electrochimica Acta, Vol.60, pp.23-30
Keywords
ThiolAcrylatePhotopolymerizationGel polymer electrolyte (GPE)Lithium secondary batteries
Abstract
Highly ion-conductive gel polymer electrolyte (GPE) with mechanical flexibility is developed by incorporating liquid electrolyte into polymer films that are fabricated by initiator-free photopolymerization of poly(ethylene glycol) dimethacrylate (acrylate monomer) and pentaerythritol tetrakis (3-mercaptopropionate) (thiol monomer) blend. When UV is irradiated on the blend, the thiol monomers themselves produce radicals to initiate the polymerization. GPEs with 40-50 wt.% of thiol monomer content show mechanically free standing characteristics with sufficient flexibility. The ionic conductivity of the GPE reaches 1.1 x 10(-3) S cm(-1) at 25 degrees C and is thus high enough to be applied for lithium secondary batteries. The GPE is electrochemically stable up to 4.4V versus Li/Li+ and the unit cells consisting of LiCoO2/GPE/lithium metal show good cycling performance. This GPE is thus considered a good electrolyte candidate for future flexible and wearable lithium secondary batteries. (C) 2011 Elsevier Ltd. All rights reserved.
ISSN
0013-4686
URI
http://hdl.handle.net/10371/164558
DOI
https://doi.org/10.1016/j.electacta.2011.10.072
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College of Engineering/Engineering Practice School (공과대학/대학원)Dept. of Chemical and Biological Engineering (화학생물공학부)Journal Papers (저널논문_화학생물공학부)
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