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Stable cycling of double-walled silicon nanotube battery anodes through solid-electrolyte interphase control

Cited 1,680 time in Web of Science Cited 1,537 time in Scopus
Authors
Wu, Hui; Chan, Gerentt; Choi, Jang Wook; Ryu, Ill; Yao, Yan; McDowell, Matthew T.; Lee, Seok Woo; Jackson, Ariel; Yang, Yuan; Hu, Liangbing; Cui, Yi
Issue Date
2012-05
Citation
Nature Nanotechnology, Vol.7 No.5, pp.309-314
Abstract
Although the performance of lithium ion-batteries continues to improve, their energy density and cycle life remain insufficient for applications in consumer electronics, transport and large-scale renewable energy storage(1-5). Silicon has a large charge storage capacity and this makes it an attractive anode material, but pulverization during cycling and an unstable solid-electrolyte interphase has limited the cycle life of silicon anodes to hundreds of cycles(6-11). Here, we show that anodes consisting of an active silicon nanotube surrounded by an ion-permeable silicon oxide shell can cycle over 6,000 times in half cells while retaining more than 85% of their initial capacity. The outer surface of the silicon nanotube is prevented from expansion by the oxide shell, and the expanding inner surface is not exposed to the electrolyte, resulting in a stable solid-electrolyte interphase. Batteries containing these double-walled silicon nanotube anodes exhibit charge capacities approximately eight times larger than conventional carbon anodes and charging rates of up to 20C (a rate of 1C corresponds to complete charge or discharge in one hour).
ISSN
1748-3387
URI
http://hdl.handle.net/10371/164582
DOI
https://doi.org/10.1038/NNANO.2012.35
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College of Engineering/Engineering Practice School (공과대학/대학원)Dept. of Chemical and Biological Engineering (화학생물공학부)Journal Papers (저널논문_화학생물공학부)
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