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Combined CO2-philicity and ordered mesoporosity for highly selective CO2 capture at high temperatures

Cited 74 time in Web of Science Cited 75 time in Scopus
Authors
Lee, Ji Hoon; Lee, Hyeon Jeong; Lim, Soo Yeon; Kim, Byung Gon; Choi, Jang Wook
Issue Date
2015-06
Citation
Journal of the American Chemical Society, Vol.137 No.22, pp.7210-7216
Abstract
Various dry sorbents have been lately introduced as promising media to capture carbon dioxide (CO2). However, it is still desirable to further improve their performance in diverse aspects, and high temperature selectivity of CO2 over other gases is clearly one of them. Here, we report a co-assembly approach to turn nonporous melamine resin to a highly ordered mesoporous polymeric network (space group: Im (3) over barm) containing high nitrogen content (similar to 18 at%). This mesoporous network shows anomalously increasing CO2/N-2 selectivity with temperature rise, with the selectivity at 323 K reaching 117 (Henry method). This selectivity behavior is attributed to a combined effect of the high nitrogen content allowing for high binding affinity with CO2 and well-defined mesopores (2.5-2.9 nm) accelerating release of N-2 with temperature rise. The given orthogonal approach suggests a new direction in designing dry sorbents with excellent selectivities at high temperatures.
ISSN
0002-7863
URI
http://hdl.handle.net/10371/164693
DOI
https://doi.org/10.1021/jacs.5b03579
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College of Engineering/Engineering Practice School (공과대학/대학원)Dept. of Chemical and Biological Engineering (화학생물공학부)Journal Papers (저널논문_화학생물공학부)
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