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Redox-Sensitive Facet Dependency in Etching of Ceria Nanocrystals Directly Observed by Liquid Cell TEM

Cited 4 time in Web of Science Cited 1 time in Scopus
Authors
Sung, Jongbaek; Choi, Back Kyu; Kim, Byunghoon; Kim, Byung Hyo; Kim, Joodeok; Lee, Donghoon; Kim, Sungin; Kang, Kisuk; Hyeon, Taeghwan; Park, Jungwon
Issue Date
2019-11
Citation
Journal of the American Chemical Society, Vol.141 No.46, pp.18395-18399
Abstract
Defining the redox activity of different surface facets of ceria nanocrystals is important for designing an efficient catalyst. Especially in liquid-phase reactions, where surface interactions are complicated, direct investigation in a native environment is required to understand the facet-dependent redox properties. Using liquid cell TEM, we herein observed the etching of ceria-based nanocrystals under the control of redox-governing factors. Direct nanoscale observation reveals facet-dependent etching kinetics, thus identifying the specific facet ({100} for reduction and {111} for oxidation) that governs the overall etching under different chemical conditions. Under each redox condition, the contribution of the predominant facet increases as the etching reactivity increases.
ISSN
0002-7863
URI
http://hdl.handle.net/10371/164952
DOI
https://doi.org/10.1021/jacs.9b09508
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College of Engineering/Engineering Practice School (공과대학/대학원)Dept. of Chemical and Biological Engineering (화학생물공학부)Journal Papers (저널논문_화학생물공학부)
College of Engineering/Engineering Practice School (공과대학/대학원)Dept. of Chemical and Biological Engineering (화학생물공학부)Chemical Convergence for Energy and Environment (에너지환경 화학융합기술전공)Journal Papers (저널논문_에너지환경 화학융합기술전공)
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