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Bio-inspired Molecular Redesign of a Multi-redox Catholyte for High-Energy Non-aqueous Organic Redox Flow Batteries

Cited 4 time in Web of Science Cited 5 time in Scopus
Authors
Kwon, Giyun; Lee, Kyunam; Lee, Myeong Hwan; Lee, Byungju; Lee, Sechan; Jung, Sung-Kyun; Ku, Kyojin; Kim, Jihyeon; Park, Soo Young; Kwon, Ji Eon; Kang, Kisuk
Issue Date
2019-10
Citation
CHEM, Vol.5 No.10, pp.2642-2656
Abstract
Redox-active organic materials (ROMs) have recently attracted significant attention for redox flow batteries (RFBs) to achieve green and cost-efficient energy storage. In particular, multi-redox ROMs have shown great promise, and further tailoring of these ROMs would yield RFB technologies with the highest possible energy density. Here, we present a phenazine-based catholyte material, 5,10-bis(2-methoxyethyl)-5,10-dihydrophenazine (BMEPZ), that undergoes two single-electron redox reactions at high redox potentials (-0.29 and 0.50 V versus Fc/Fc(+)) with enhanced solubility (0.5 M in acetonitrile), remarkable chemical stability, and fast kinetics. Moreover, an all-organic flow battery exhibits cell voltages of 1.2 and 2.0 V when coupled with 9-fluorenone (FL) as an anolyte. It shows capacity retention of 99.94% per cycle over 200 cycles and 99.3% per cycle with 0.1 M and 0.4 M BMEPZ catholyte, respectively. Notably, the BMEPZ/FL couple results in the highest energy density (similar to 17 Wh L-1) among the non-aqueous all- organic RFBs reported to date.
ISSN
2451-9294
URI
http://hdl.handle.net/10371/164962
DOI
https://doi.org/10.1016/j.chempr.2019.07.006
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College of Engineering/Engineering Practice School (공과대학/대학원)Dept. of Material Science and Engineering (재료공학부) Journal Papers (저널논문_재료공학부)
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