Browse

Lithium-excess olivine electrode for lithium rechargeable batteries

DC Field Value Language
dc.contributor.authorPark, Kyu-Young-
dc.contributor.authorPark, Inchul-
dc.contributor.authorKim, Hyungsub-
dc.contributor.authorYoon, Gabin-
dc.contributor.authorGwon, Hyeokjo-
dc.contributor.authorCho, Yongbeom-
dc.contributor.authorYun, Young Soo-
dc.contributor.authorKim, Jung-Joon-
dc.contributor.authorLee, Seongsu-
dc.contributor.authorAhn, Docheon-
dc.contributor.authorKim, Yunok-
dc.contributor.authorKim, Haegyeom-
dc.contributor.authorHwang, Insang-
dc.contributor.authorYoon, Won-Sub-
dc.contributor.authorKang, Kisuk-
dc.date.accessioned2020-04-25T07:57:02Z-
dc.date.available2020-04-25T07:57:02Z-
dc.date.issued2016-09-
dc.identifier.citationEnergy and Environmental Sciences, Vol.9 No.9, pp.2902-2915-
dc.identifier.issn1754-5692-
dc.identifier.other44156-
dc.identifier.urihttp://hdl.handle.net/10371/165037-
dc.description.abstractLithium iron phosphate (LFP) has attracted tremendous attention as an electrode material for next-generation lithium-rechargeable battery systems due to the use of low-cost iron and its electrochemical stability. While the lithium diffusion in LFP, the essential property in battery operation, is relatively fast due to the one-dimensional tunnel present in the olivine crystal, the tunnel is inherently vulnerable to the presence of Fe-Li anti-site defects (Fe ions in Li ion sites), if any, that block the lithium diffusion and lead to inferior performance. Herein, we demonstrate that the kinetic issue arising from the Fe-Li defects in LFP can be completely eliminated in lithium-excess olivine LFP. The presence of an excess amount of lithium in the Fe ion sites (Li-Fe) energetically destabilizes the Fe-Li-related defects, resulting in reducing the amount of Fe defects in the tunnel. Moreover, we observe that the spinodal decomposition barrier is notably reduced in lithium-excess olivine LFP. The presence of Li-Fe and the absence of Fe-Li in lithium-excess olivine LFP additionally induce faster kinetics, resulting in an enhanced rate capability and a significantly reduced memory effect. The lithium-excess concept in the electrode crystal brings up unexpected properties for the pristine crystal and offers a novel and interesting approach to enhance the diffusivity and open up additional diffusion paths in solid-state ionic conductors.-
dc.titleLithium-excess olivine electrode for lithium rechargeable batteries-
dc.typeArticle-
dc.contributor.AlternativeAuthor강기석-
dc.identifier.doi10.1039/c6ee01266c-
dc.citation.journaltitleEnergy and Environmental Sciences-
dc.identifier.scopusid2-s2.0-84984871148-
dc.citation.endpage2915-
dc.citation.number9-
dc.citation.startpage2902-
dc.citation.volume9-
dc.identifier.urlhttps://pubs.rsc.org/en/Content/ArticleLanding/2016/EE/C6EE01266C#!divAbstract-
dc.identifier.rimsid44156-
dc.identifier.sci000382746300017-
dc.description.isOpenAccessN-
dc.contributor.affiliatedAuthorKang, Kisuk-
Appears in Collections:
College of Engineering/Engineering Practice School (공과대학/대학원)Dept. of Material Science and Engineering (재료공학부) Journal Papers (저널논문_재료공학부)
Files in This Item:
There are no files associated with this item.
  • mendeley

Items in S-Space are protected by copyright, with all rights reserved, unless otherwise indicated.

Browse