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Understanding the degradation mechanisms of LiNi0.5Co 0.2Mn0.3O2 cathode material in lithium ion batteries

Cited 509 time in Web of Science Cited 539 time in Scopus
Authors
Jung, Sung-Kyun; Gwon, Hyeokjo; Hong, Jihyun; Park, Kyu-Young; Seo, Dong-Hwa; Kim, Haegyeom; Hyun, Jangsuk; Yang, Wooyoung; Kang, Kisuk
Issue Date
2014-01
Citation
Advanced Energy Materials, Vol.4 No.1, p. 1300787
Abstract
LiNixCoyMnzO2 (NCM, 0 <= x, y, z < 1) has become one of the most important cathode materials for next-generation lithium (Li) ion batteries due to its high capacity and cost effectiveness compared with LiCoO2. However, the high-voltage operation of NCM (>4.3 V) required for high capacity is inevitably accompanied by a more rapid capacity fade over numerous cycles. Here, the degradation mechanisms of LiNi0.5Co0.2Mn0.3O2 are investigated during cycling under various cutoff voltage conditions. The surface lattice structures of LiNi0.5Co0.2Mn0.3O2 are observed to suffer from an irreversible transformation; the type of transformation depends on the cutoff voltage conditions. The surface of the pristine rhombohedral phase tends to transform into a mixture of spinel and rock salt phases. Moreover, the formation of the rock salt phase is more dominant under a higher voltage operation (approximate to 4.8 V), which is attributable to the highly oxidative environment that triggers the oxygen loss from the surface of the material. The presence of the ionically insulating rock salt phase may result in sluggish kinetics, thus deteriorating the capacity retention. This implies that the prevention of surface structural degradation can provide the means to produce and retain high capacity, as well as stabilize the cycle life of LiNi0.5Co0.2Mn0.3O2 during high-voltage operations.
ISSN
1614-6832
URI
http://hdl.handle.net/10371/165098
DOI
https://doi.org/10.1002/aenm.201300787
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College of Engineering/Engineering Practice School (공과대학/대학원)Dept. of Material Science and Engineering (재료공학부) Journal Papers (저널논문_재료공학부)
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