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M-CPBA mediated oxidation of (benzenesulfonyl)ketene s,s-acetals and 7,12-dihydro[5,6][1,3]thiazepino[3,2-α] benzimidazole 6,6-dioxides : regio- and stereochemistry

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Authors

이재상

Advisor
김경태
Issue Date
2003
Publisher
서울대학교 대학원
Keywords
(벤젠술포닐)키틴 SS-아세탈m-CPBA2-알킬술포닐메탄슐포닐-1-아릴에탄온모노-술폭사이드 (E, Z)디-술폭사이드 ((R, S), (R, R))디술폰 (E, Z)트리술폰에폭시트리술폰디-술폭사이드 (R, S) 와 (R, R) 사이의 이성질화1-아릴-22-비스(알킬술포닐)에탄온2-알킬술포닐메탄슐포닐-1-아릴에탄온1, 3-디음이온 반응벤즈이미다졸7-비스(알킬술파닐메틸렌)-12-디하이드로[5, 6][1, 3]티아제피노[3, 2-a]벤즈이미다졸 66-디옥사이드1-(2-알킬술파닐에테닐)벤즈-13-디하이드로-벤즈이미다졸-2-온모노-N-치환의 다양한 벤즈이미다졸-2-온7, 12-디하이드로[5, 6][1, 3]티아제피노[3, 2-a]벤즈이미다졸 66-디옥사이드알킬 프로피올레이트(benzenesulfonyl)ketene sS-acetalsM-cpbaMonosulfinylsulfonesDisulfinylsulfonesEnantiomeric mixtureStereochemistrySteric and electronic effectsX-ray single crystalTrisulfoneEpoxysulfones1-aryl-22-bis(alkylsulfonyl)ethanonesIsomerization(r, S)-2-(4-anisyl)-2-benzenesulfonyl-11-bis(methanesulfinyl)etheneOf 712-dihydro[5, 6][1, 3]thiazepino [3, 2-a]benzi-midazole 66-dioxideGave 7-bis(alkylsulfanylmethene)-12-hydro[5, 6][1, 3] thiazepino[3, 2-a]benzimidazole 66-dioxide(e)/(z)-7-(alkylsulfanyl-alkylsulfinylmethene)-12-hydro[5, 6][1, 3]thiazepino[3, 2-a]benzimidazole 66-dioxide1-(2-alkylsulfanylethynylbenzyl)-13-dihydrobenzimidazol-2-one
Description
Thesis (doctoral)--서울대학교 대학원 :화학부,2003.
Language
English
URI
http://dcollection.snu.ac.kr:80/jsp/common/DcLoOrgPer.jsp?sItemId=000000058213

https://hdl.handle.net/10371/19909
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