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Chemical Activation of AgNO3 to Form Olefin Complexes Induced by Strong Coordinative Interactions with Phthalate Oxygens of Poly(ethylene phthalate)

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Authors
Kang, Sang Wook; Kim, Jong Hak; Char, Kookheon; Kang, Yong Soo
Issue Date
2006-04-28
Publisher
American Chemical Society
Citation
Ind. Eng. Chem. Res., 2006, 45, 4011-4014
Abstract
AgNO3 is inactive as an olefin complexing agent and is not easily reduced to metallic silver. Poly(ethylene phthalate) (PEP) was used to induce the dissociation of AgNO3 into free ions, resulting in more active complexation with propylene. The free ion formation is mainly due to the strong interactions of silver ions with phthalate oxygens, as confirmed by Raman spectroscopy and X-ray photoelectron spectroscopy (XPS). Furthermore, increased silver ion complexation with propylene in the electrolyte membrane of PEP/AgNO3 polymer was confirmed by the improved separation performance of propylene/propane mixtures, compared to a poly(2-ethyl-2-oxazoline) (POZ)/AgNO3 membrane. In addition, the separation performance for the former remained unchanging for a longer period of time than that for the latter.
ISSN
0888-5885 (print)
1520-5045 (online)
Language
English
URI
http://hdl.handle.net/10371/5796
DOI
https://doi.org/10.1021/ie051328+
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College of Engineering/Engineering Practice School (공과대학/대학원)Dept. of Chemical and Biological Engineering (화학생물공학부)Journal Papers (저널논문_화학생물공학부)
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