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Preparation of Pt/NiO-C electrocatalyst and heat-treatment effect on its electrocatalytic performance for methanol oxidation
Cited 65 time in
Web of Science
Cited 62 time in Scopus
- Authors
- Issue Date
- 2010
- Publisher
- Elsevier
- Citation
- International Journal of Hydrogen Energy 2010;35:313–320
- Keywords
- Direct methanol fuel cell ; Pt catalyst ; NiO ; Methanol oxidation ; Heat-treatment
- Abstract
- Pt catalyst supported on Vulcan XC-72R containing 5 wt% NiO (Pt/NiO–C) showed larger
electrochemical active surface area and higher electrochemical activity for methanol
oxidation than Pt catalyst supported on Vulcan XC-72R using polyol method without NiO
addition. Prepared Pt/NiO–C electrocatalyst was heat-treated at four temperatures
(200, 400, 600, and 800 C) in flowing N2. X-ray diffraction and temperature-programmed
desorption results indicated that NiO was reduced to Ni in inert N2 during heat-treatments
at temperatures above or equal to 400 C, while oxygen from NiO reacted with carbon
support due to the catalytic effect of Pt. The reduced Ni formed an alloy with Pt, which,
according to the X-ray photoelectron spectroscopy data, resulted in a shift to a lower
binding energy of Pt 4f electrons. The Pt/NiO–C electrocatalyst heat-treated at 400 C
showed the best activity in methanol oxidation due to the change in Pt electronic structure
by Ni and the minimal aggregation of Pt particles.
- ISSN
- 0360-3199
- Language
- English
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