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Synthesis and Light-Emitting Properties of New Polyimides Containing Ethynylene Units in the Main Chain

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Authors
Chi, Jun Ho; Park, Se Hee; Lee, Chang-Lyoul; Kim, Jang-Joo; Jung, Jin Chul
Issue Date
2007-06-28
Publisher
Wiley-Blackwell
Citation
Macromol. Mater. Eng. 2007, 292, 844
Keywords
electroluminescent polyimideethynylene-containing polyimidelight-emitting polyimidephotoluminescent polyimidepolyimide
Abstract
Two new polyimides (ODA-PI and HDA-PI) having 1,4-phenylenediethynylene unit and octyloxy groups were synthesized. Judging from inherent viscosities of their precursor PAAs (1.42 and 1.62 dL · g-1), the two PIs were very high in molecular weight. Casting and thermal imidization of PAAs results polyimides with good-quality films. They were stable up to 364 °C and showed no crystallites. UV-vis and PL spectra in NMP solutions of both PIs showed maxima at 442 and 501 nm, respectively, while PL spectra in 10 µm thick films exhibited a maximum at 540 nm. CV indicates that two PIs were electrochemically active in redox region. The devices with construction of ITO/PEDOT/PIs/BAlq3/LiF/Al exhibited turn-on voltages of 6.5 V in ODA-PI and 7.5 V in HDA-PI and emitted a bright bluish-green light. ODA-PI and HDA-PI showed maximum luminescence of 256 and 316 cd · cm-2, respectively, at the same voltage of 12 V.
ISSN
1438-7492 (online)
1439-2054 (online)
Language
English
URI
http://hdl.handle.net/10371/7009
DOI
https://doi.org/10.1002/mame.200700067
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College of Engineering/Engineering Practice School (공과대학/대학원)Dept. of Material Science and Engineering (재료공학부) Journal Papers (저널논문_재료공학부)
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