SHERP

Spectroscopic analysis of l-histidine adsorbed on gold and silver nanoparticle surfaces investigated by surface-enhanced Raman scattering

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Authors
Lim, Jong Kuk; Kim, Youngmin; Lee, So Yeong; Joo, Sang-Woo
Issue Date
2007-05-07
Publisher
Elsevier
Citation
Spectrochim. Acta A 69 (2008) 286
Keywords
l-HistidineAuAgSERSDFT calculation
Abstract
The adsorption of l-histidine on gold (Au) and silver (Ag) nanoparticle surfaces has been comparatively analyzed by means of surface-enhanced Raman scattering (SERS). The SERS spectra of l-histidine on Ag were found to be quite different from those on Au, indicating dissimilar adsorption structures depending on metal substrates. Most peaks of l-histidine on Ag appeared to be due to coordination via the carboxylate (COO−) group with an imidazole ring of fairly upright geometry, whereas on Au it was assumed to adsorb with a rather flat geometry. A density functional theory (DFT) calculation was performed at the level of B3LYP/LANL2DZ to estimate the energetic stability of the binding of the imidazole ring and the carboxylate group of l-histidine with the Ag and Au atoms, respectively. Based on the DFT calculation, the carboxylate group of l-histidine was predicted to bind more favorably to Ag than to Au, and this was in line with our SERS spectral analysis.
ISSN
1386-1425
Language
English
URI
http://hdl.handle.net/10371/7604
DOI
https://doi.org/10.1016/j.saa.2007.05.007
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College of Veterinary Medicine (수의과대학)Dept. of Veterinary Medicine (수의학과)Journal Papers (저널논문_수의학과)
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