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Study on energy efficiency and cyclability of anode material in Li ion battery
리튬이온 배터리 음극재료의 에너지 효율과 주기 성능에 대한 연구

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dc.contributor.advisor조맹효-
dc.contributor.author김성섭-
dc.date.accessioned2017-07-13T06:28:44Z-
dc.date.available2017-07-13T06:28:44Z-
dc.date.issued2017-02-
dc.identifier.other000000141159-
dc.identifier.urihttps://hdl.handle.net/10371/118586-
dc.description학위논문 (박사)-- 서울대학교 대학원 : 기계항공공학부, 2017. 2. 조맹효.-
dc.description.abstractIn this dissertation, a study on the energy dissipation and performance degradation of silicon anode of lithium ion batteries have been investigated by chemo-mechanical coupling finite element method. Galvanostatic charge – discharge cycle is simulated, and the energy dissipation is calculated from entropy production due to diffusion and plastic deformation. Both silicon nanowire and silicon nanofilm anode have been simulated to observe the effect of anode geometry on dissipation. Yield strength, charge range and charge speed are varied in order to study the effect of material properties and charging condition. It is observed that whereas diffusion dissipation dominates in nanowire anode, plastic dissipation dominates in nanofilm anode. Energy dissipation as a function of charge range and charge speed have been presented for both nanowire and nanofilm andes. On the other hand, the initiation and propagation of crack in galvanostatic charge – discharge cycle have been simulated using element failure method. Tensile strength is used as the crack initiation criteria, and the fracture energy and J-integral is used as the crack propagation criteria. Crack propagation direction is determined by the direction of first pricipal stress. When a crack exists in a nanowire, the dissipation by diffusion and plastic has been increased, apart from the dissipation by crack. The increase of plastic and dissipation energy dissipation owing to the existence of crack is ploted, and the value increases as the nanowire radius increases. Calculation has been performed for the initial center crack and initial surface crack case, and it is observed whereas the initial center crack tends to grow straightly, the initial surface crack tends to be vent owing to higher compressive stress in the inner part at discharging state.-
dc.description.tableofcontents1 Introduction 1
1.1 Motivations 1
1.2 Research trends 2
2 Framework of diffusion-deformation couplig simulation 8
2.1 Diffusion-deformation coupling formulation 8
3 Anode design for energy-efficient battery charging 15
3.1 Simulation modeling 15
3.2 Energy dissipation 18
3.3 Validation of the present method 19
3.4 Effect of yield strength on energy dissipation 21
3.4.1 Spacial distribution of lithium concentration and stress 21
3.4.2 Effect of yield strength on energy dissipation and dissipation rate 23
3.4.3 Effect of boundary condition on energy dissipation 25
3.5 Effect of , , and on energy dissipation 27
3.5.1 Energy dissipation in nanowire 28
3.5.2 Energy dissipation in nanofilm 30
4 Crack initiation and propagation under Galvanostatic charging cycle in silicon nanowire 64
4.1 Element failure method 64
4.2 Simulation modeling 69
4.3 Results 71
4.3.1 Convergency of the solution with respect to the mesh density 71
4.3.2 Initial crack at the center of nanowire 71
4.3.3 Initial crack at the surface of nanowire 72
5 Conclusions 94
References 96
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dc.formatapplication/pdf-
dc.format.extent3876613 bytes-
dc.format.mediumapplication/pdf-
dc.language.isoen-
dc.publisher서울대학교 대학원-
dc.subjectLithium-ion batteries-
dc.subjectsilicon anode-
dc.subjectnanowire-
dc.subjectnanofilm-
dc.subjectenergy dissipation-
dc.subjectgalvanostatic charge-discharge cycle-
dc.subjectelement failure method-
dc.subjectcrack propagation.-
dc.subject.ddc621-
dc.titleStudy on energy efficiency and cyclability of anode material in Li ion battery-
dc.title.alternative리튬이온 배터리 음극재료의 에너지 효율과 주기 성능에 대한 연구-
dc.typeThesis-
dc.contributor.AlternativeAuthorSeongseop Kim-
dc.description.degreeDoctor-
dc.citation.pagesxiv, 101-
dc.contributor.affiliation공과대학 기계항공공학부-
dc.date.awarded2017-02-
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College of Engineering/Engineering Practice School (공과대학/대학원)Dept. of Mechanical Aerospace Engineering (기계항공공학부)Theses (Ph.D. / Sc.D._기계항공공학부)
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