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Poly(3,4-dimethyl-5-vinylthiazolium)s catalyzed reactions : 3,4-다이메틸-5-바이닐싸이아졸리움 고분자 촉매를 이용한 반응들
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- Authors
- Advisor
- 정영근
- Major
- 자연과학대학 화학부
- Issue Date
- 2015-08
- Publisher
- 서울대학교 대학원
- Keywords
- Polymer precatalysts ; Poly(vinylthiazolium)s ; Thioesterification ; Thiol-ene click reaction ; Recycling catalyst
- Description
- 학위논문 (석사)-- 서울대학교 대학원 : 화학부 무기화학전공, 2015. 8. 정영근.
- Abstract
- Poly(3,4-dimethyl-5-vinylthiazolium)s were synthesized from 3,4-dimethyl-5-vinylthiazole via free radical polymerization. It examined as polymer precatalysts in the presence of DBU for the thioesterification of aldehydes with thiols and for the thiol-ene click reaction of styrene with thiols. The poly(5-vinylthiazolium)s had excellent catalytic activity and could be reused more then three times without loss of activity.
- Language
- English
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