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The characteristics and the performance of dual air supply polymer electrolyte membrane fuel cell : 고분자 전해지막 연료전지의 공기 중간 주입 시 특성 및 성능

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dc.contributor.advisor김민수-
dc.contributor.author윤채영-
dc.date.accessioned2017-10-31T07:34:01Z-
dc.date.available2017-10-31T07:34:01Z-
dc.date.issued2017-08-
dc.identifier.other000000145026-
dc.identifier.urihttps://hdl.handle.net/10371/137353-
dc.description학위논문 (석사)-- 서울대학교 대학원 공과대학 기계항공공학부, 2017. 8. 김민수.-
dc.description.abstractAfter industrialization, environmental pollution and global warming become more crucial than before to living things and people on earth. So researchers focus on developing eco-friendly, renewable energy. Polymer electrolyte membrane fuel cell (PEMFC) is regarded as one of the promising power generator. PEMFC generates electricity by reaction of hydrogen and oxygen. So PEMFC produces water and heat after reaction, that doesnt make pollutant like sulfur oxide (SOx) and nitrogen oxide (NOx). PEMFC has also other charming advantages, High efficiency, high power density and operation at low temperature.
But there are some problems to be solved for commercialization and popularization of PEMFC like Water management, flow distribution, high cost of Pt-catalyst, etc.
If flow doesnt distribute uniformly inside fuel cell, it cannot show high performance. In addition, un-uniform gas distribution can cause unstable operation of fuel cell and durability problem. So many researchers make studies on flow distribution inside fuel cell.
In this study, dual air supply concept was applied to fuel cell to enhance the performance of fuel cell by improving flow distribution.
For dual air supply fuel cell, an additional air inlet port was added to normal fuel cell. Through this additional air inlet port and main air inlet, air can be divided and supplied to fuel cell. When experiments were conducted using dual air supply fuel cell, it is necessary to air flow ratio through main and an additional air inlet. So, experiments were carried out first on various air flow ratio conditions. After that, operating characteristics of dual air supply fuel cell was investigated. Stoichiometric ratio of air and relative humidity of air were selected in each experiment, operating characteristics of dual air supply fuel cell was figured out.
Also, Stability characteristics and EIS measurement were investigated. As written before, Voltage fluctuation was analyzed on various air flow ratio conditions, then results were compared that of normal fuel cell.
Lastly, EIS measurement was conducted on various air flow ratio. Reactance and resistance value could be gained. Using that, performance difference in each various air flow ratio conditions was analyzed.
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dc.description.tableofcontentsChapter 1. Introduction 1
1.1 Background of the study 1
1.2 Literature review 4
1.3 Objectives and scopes 8
Chapter 2. Experimental setup and unit cell for dual air supply 10
2.1 Introduction 10
2.2 Bipolar plate for dual air supply 10
2.3 Dual air supply fuel cell 11
Chapter 3. Operating characteristics of dual air supply PEMFC 17
3.1 Introduction 17
3.2 Performance comparison on various air supply ratio 17
3.2.1 Experimental conditions 18
3.2.2 I-V curve comparison 18
3.2.3 I-P curve comparison 19
3.3 Performance comparison on varisous air stoichiometric ratio(SR) conditions 25
3.3.1 Experimental conditions 25
3.3.2 I-V performance on various air SR conditions 25
3.4 Performance measurement on supplying non-humidified or humidified air to an additional inlet 30
3.4.1 Experimental conditions 30
3.4.2 Experimental results 31
3.5 Additional experiment: comparison of activation cycle 38
3.6 Summary 40
Chapter 4. Stability characteristics and EIS measurement of dual air supply PEMFC 41
4.1 Introduction 41
4.2 Stability characteristics 41
4.2.1 Experimental conditions 42
4.2.2 Experimental results 42
4.3 EIS measurement 53
4.3.1 Experimental conditions 53
4.3.2 Experimental results 53
4.4 Summary 59
Chapter 5. Conclusion 60
References 62
Abstract (Korean) 65
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dc.formatapplication/pdf-
dc.format.extent1053845 bytes-
dc.format.mediumapplication/pdf-
dc.language.isoen-
dc.publisher서울대학교 대학원-
dc.subjectpolymer electrolyte membrane fuel cell-
dc.subjectdual air supply-
dc.subjectflow distribution-
dc.subjectparallel channel-
dc.subject.ddc621-
dc.titleThe characteristics and the performance of dual air supply polymer electrolyte membrane fuel cell-
dc.title.alternative고분자 전해지막 연료전지의 공기 중간 주입 시 특성 및 성능-
dc.typeThesis-
dc.description.degreeMaster-
dc.contributor.affiliation공과대학 기계항공공학부-
dc.date.awarded2017-08-
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