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Rhodium-catalyzed reactions using alcohol as a carbon monoxide, nucleophile, hydration and alkylating source
로듐촉매를 사용하여 알코올을 일산화탄소와 친핵체, 수화 및 알킬화 공급원으로 이용하는 반응 연구

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Authors
박하원
Advisor
정영근
Major
자연과학대학 화학부
Issue Date
2017-08
Publisher
서울대학교 대학원
Keywords
rhodiumesteralcoholalkynecarbonylationchiralα-alkylated ketonehydrationalkylationaddition reaction
Description
학위논문 (석사)-- 서울대학교 대학원 자연과학대학 화학부, 2017. 8. 정영근.
Abstract
A CO-gas-free rhodium-catalyzed alkoxycarbonylation of aryl iodide with alcohols has been developed. Alcohols, with/without the aid of an aldehyde, were used as a carbon monoxide and nucleophile source.
Moreover, atom economic rhodium-catalyzed synthesis of chiral α-alkylated ketone from alkyne with benzyl alcohols has been developed. Benzyl alcohols were used as a hydration and alkylation source.
Language
English
URI
https://hdl.handle.net/10371/138109
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College of Natural Sciences (자연과학대학)Dept. of Chemistry (화학부)Theses (Master's Degree_화학부)
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