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A Family of High-Performance Cathode Materials for Na-ion Batteries, Na-3(VO1-xPO4)(2) F1+2x (0 <= x <= 1): Combined First-Principles and Experimental Study
DC Field | Value | Language |
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dc.contributor.author | Park, Young-Uk | - |
dc.contributor.author | Seo, Dong-Hwa | - |
dc.contributor.author | Kim, Hyungsub | - |
dc.contributor.author | Kim, Jongsoon | - |
dc.contributor.author | Lee, Seongsu | - |
dc.contributor.author | Kim, Byoungkook | - |
dc.contributor.author | Kang, Kisuk | - |
dc.date.accessioned | 2020-04-25T08:09:52Z | - |
dc.date.available | 2020-04-25T08:09:52Z | - |
dc.date.created | 2020-02-19 | - |
dc.date.created | 2020-02-19 | - |
dc.date.issued | 2014-08 | - |
dc.identifier.citation | Advanced Functional Materials, Vol.24 No.29, pp.4603-4614 | - |
dc.identifier.issn | 1616-301X | - |
dc.identifier.other | 91877 | - |
dc.identifier.uri | https://hdl.handle.net/10371/165101 | - |
dc.description.abstract | Room-temperature Na-ion batteries (NIBs) have recently attracted attention as potential alternatives to current Li-ion batteries (LIBs). The natural abundance of sodium and the similarity between the electrochemical properties of NIBs and LIBs make NIBs well suited for applications requiring low cost and long-term reliability. Here, the first successful synthesis of a series of Na-3(VO1-xPO4)(2)F1+2x (0 x 1) compounds as a new family of high-performance cathode materials for NIBs is reported. The Na-3(VO1-xPO4)(2)F1+2x series can function as high-performance cathodes for NIBs with high energy density and good cycle life, although the redox mechanism varies depending on the composition. The combined first-principles calculations and experimental analysis reveal the detailed structural and electrochemical mechanisms of the various compositions in solid solutions of Na-3(VOPO4)(2)F and Na3V2(PO4)(2)F-3. The comparative data for the Na (y) (VO1-xPO4)(2)F1+2x electrodes show a clear relationship among V3+/V4+/V5+ redox reactions, Na+-Na+ interactions, and Na+ intercalation mechanisms in NIBs. The new family of high-energy cathode materials reported here is expected to spur the development of low-cost, high-performance NIBs. | - |
dc.language | 영어 | - |
dc.publisher | John Wiley & Sons Ltd. | - |
dc.title | A Family of High-Performance Cathode Materials for Na-ion Batteries, Na-3(VO1-xPO4)(2) F1+2x (0 <= x <= 1): Combined First-Principles and Experimental Study | - |
dc.type | Article | - |
dc.contributor.AlternativeAuthor | 강기석 | - |
dc.identifier.doi | 10.1002/adfm.201400561 | - |
dc.citation.journaltitle | Advanced Functional Materials | - |
dc.identifier.wosid | 000340461400005 | - |
dc.identifier.scopusid | 2-s2.0-84905446560 | - |
dc.citation.endpage | 4614 | - |
dc.citation.number | 29 | - |
dc.citation.startpage | 4603 | - |
dc.citation.volume | 24 | - |
dc.identifier.sci | 000340461400005 | - |
dc.description.isOpenAccess | N | - |
dc.contributor.affiliatedAuthor | Kang, Kisuk | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.subject.keywordPlus | SODIUM RECHARGEABLE BATTERIES | - |
dc.subject.keywordPlus | ELECTROCHEMICAL PROPERTIES | - |
dc.subject.keywordPlus | ENERGY-STORAGE | - |
dc.subject.keywordPlus | ELECTRODE PERFORMANCE | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURE | - |
dc.subject.keywordPlus | LITHIUM | - |
dc.subject.keywordPlus | FLUOROPHOSPHATE | - |
dc.subject.keywordPlus | NA3V2O2X(PO4)(2)F3-2X | - |
dc.subject.keywordPlus | PYROPHOSPHATE | - |
dc.subject.keywordPlus | DIFFRACTION | - |
dc.subject.keywordAuthor | Na-ion batteries | - |
dc.subject.keywordAuthor | cathode materials | - |
dc.subject.keywordAuthor | fluorophosphates | - |
dc.subject.keywordAuthor | first-principle calculations | - |
dc.subject.keywordAuthor | sodium | - |
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