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Synthesis and electrochemical properties of layered Li0.9Ni0.45Ti0.55O2
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kang, Kisuk | - |
dc.contributor.author | Carlier, Dany | - |
dc.contributor.author | Reed, John | - |
dc.contributor.author | Arroyo, Elena M | - |
dc.contributor.author | Ceder, Gerbrand | - |
dc.contributor.author | Croguennec, L | - |
dc.contributor.author | Delmas, C | - |
dc.date.accessioned | 2020-04-25T08:28:00Z | - |
dc.date.available | 2020-04-25T08:28:00Z | - |
dc.date.created | 2020-03-20 | - |
dc.date.created | 2020-03-20 | - |
dc.date.issued | 2003-11 | - |
dc.identifier.citation | Chemistry of Materials, Vol.15 No.23, pp.4503-4507 | - |
dc.identifier.issn | 0897-4756 | - |
dc.identifier.other | 92983 | - |
dc.identifier.uri | https://hdl.handle.net/10371/165197 | - |
dc.description.abstract | New Li0.9Ni0.45Ti0.55O2 positive electrode materials were synthesized by means of ion exchange from Na0.9Ni0.45Ti0.55O2. Powder X-ray diffraction (XRD) patterns for these materials indicate that they are isostructural with alpha-NaFeO2. The degree of cation disordering in the material depends critically on the synthesis conditions. Higher temperatures and longer ion-exchange times induce more cation disordering. Surprisingly, the partially disordered phase shows better capacity retention than the least disordered phase. First-principles calculations indicated the poor capacity retention in the least disordered phase could be attributed to the migration of Ti4+ into the Li layer during the electrochemical testing. The Ti4+ migration seems to depend sensitively on the Ni2+-Ti4+ configuration in the transition metal layer. Density of states (DOS) obtained from first-principles calculations indicate that only Ni participates in the electronic conductivity and that the poor conductivity of this material could be another reason for its low specific capacity. | - |
dc.language | 영어 | - |
dc.publisher | American Chemical Society | - |
dc.title | Synthesis and electrochemical properties of layered Li0.9Ni0.45Ti0.55O2 | - |
dc.type | Article | - |
dc.contributor.AlternativeAuthor | 강기석 | - |
dc.identifier.doi | 10.1021/cm034455+ | - |
dc.citation.journaltitle | Chemistry of Materials | - |
dc.identifier.wosid | 000186598700025 | - |
dc.identifier.scopusid | 2-s2.0-0344876654 | - |
dc.citation.endpage | 4507 | - |
dc.citation.number | 23 | - |
dc.citation.startpage | 4503 | - |
dc.citation.volume | 15 | - |
dc.identifier.sci | 000186598700025 | - |
dc.description.isOpenAccess | N | - |
dc.contributor.affiliatedAuthor | Kang, Kisuk | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.subject.keywordPlus | SUBSTITUTION | - |
dc.subject.keywordPlus | TRANSITION | - |
dc.subject.keywordPlus | STABILITY | - |
dc.subject.keywordPlus | OXIDES | - |
dc.subject.keywordPlus | CHARGE | - |
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