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Generalized synthesis of metal phosphide nanorods via thermal decomposition of continuously delivered metal-phosphine complexes using a syringe pump
DC Field | Value | Language |
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dc.contributor.author | Park, Jongnam | - |
dc.contributor.author | Koo, Bonil | - |
dc.contributor.author | Yoon, Ki Youl | - |
dc.contributor.author | Hwang, Yosun | - |
dc.contributor.author | Kang, Misun | - |
dc.contributor.author | Park, Je-Geun | - |
dc.contributor.author | Hyeon, Taeghwan | - |
dc.date.accessioned | 2020-04-27T13:34:22Z | - |
dc.date.available | 2020-04-27T13:34:22Z | - |
dc.date.created | 2020-03-19 | - |
dc.date.created | 2020-03-19 | - |
dc.date.issued | 2005-06 | - |
dc.identifier.citation | Journal of the American Chemical Society, Vol.127 No.23, pp.8433-8440 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.other | 92866 | - |
dc.identifier.uri | https://hdl.handle.net/10371/165975 | - |
dc.description.abstract | We synthesized uniform-sized nanorods of transition metal phosphides from the thermal decomposition of continuously delivered metal-phosphine complexes using a syringe pump. MnP nanorods with dimensions of 8 nm x 16 nm and 6 nm x 22 nm sized were synthesized by the thermal decomposition of Mn-TOP complex, which was prepared from the reaction of Mn-2(CO)(10) and tri-n-octylphosphine (TOP), using a syringe pump with constant injection rates of 10 and 20 mL/h, respectively. When Co-TOP complex, which was prepared from the reaction of cobalt acetylacetonate and TOP, was reacted in a mixture solvent composed of octyl ether and hexadecylamine at 300 degrees C using a syringe pump, uniform 2.5 nm x 20 nm sized Co2P nanorods were generated. When cobaltocene was employed as a precursor, uniform Co2P nanorods with 5 nm x 15 nm were obtained. When Fe-TOP complex was added to trioctylphosphine oxide (TOPO) at 360 degrees C using a syringe pump and then allowed to age at 360 degrees C for 30 min, uniform-sized FeP nanorods with an average dimension of 12 nm x 500 nm were produced. Nickel phosphide (Ni2P) nanorods with 4 nm x 8 nm were synthesized successfully by thermally decomposing the Ni-TOP complex, which was synthesized by reacting acetylacetonate [Ni(acac)(2)] and TOP, We measured the magnetic properties of these nanorods, and some of the nanorods exhibited different magnetic characteristics compared to the bulk counterparts. | - |
dc.language | 영어 | - |
dc.publisher | American Chemical Society | - |
dc.title | Generalized synthesis of metal phosphide nanorods via thermal decomposition of continuously delivered metal-phosphine complexes using a syringe pump | - |
dc.type | Article | - |
dc.contributor.AlternativeAuthor | 현택환 | - |
dc.identifier.doi | 10.1021/ja0427496 | - |
dc.citation.journaltitle | Journal of the American Chemical Society | - |
dc.identifier.wosid | 000229751100051 | - |
dc.identifier.scopusid | 2-s2.0-20444503866 | - |
dc.citation.endpage | 8440 | - |
dc.citation.number | 23 | - |
dc.citation.startpage | 8433 | - |
dc.citation.volume | 127 | - |
dc.identifier.sci | 000229751100051 | - |
dc.description.isOpenAccess | N | - |
dc.contributor.affiliatedAuthor | Hyeon, Taeghwan | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.subject.keywordPlus | SOURCE MOLECULAR PRECURSORS | - |
dc.subject.keywordPlus | MAGNETIC-PROPERTIES | - |
dc.subject.keywordPlus | SEMICONDUCTOR NANOWIRES | - |
dc.subject.keywordPlus | GOLD NANORODS | - |
dc.subject.keywordPlus | INORGANIC NANOCRYSTALS | - |
dc.subject.keywordPlus | SOLVENTLESS SYNTHESIS | - |
dc.subject.keywordPlus | MEDIATED SYNTHESIS | - |
dc.subject.keywordPlus | COBALT NANORODS | - |
dc.subject.keywordPlus | SINGLE-CRYSTAL | - |
dc.subject.keywordPlus | ZNS NANOWIRES | - |
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