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Electrolysis of iron with oxygen gas evolution from molten sodium borate electrolytes
Cited 4 time in
Web of Science
Cited 4 time in Scopus
- Authors
- Issue Date
- 2021-10
- Publisher
- Maney Publishing
- Citation
- Ironmaking and Steelmaking, Vol.48 No.9, pp.1030-1037
- Abstract
- Molten oxide electrolysis can be used to reduce the carbon dioxide emissions from ironmaking. In this paper, we electrochemically decompose iron oxide (Fe2O3) into iron (Fe) and oxygen (O-2) using boron trioxide and sodium oxide (B2O3-Na2O) as the molten oxide electrolyte at 1000 degrees C that is less than the temperature of other molten oxide electrolysis. The formation of Fe at the cathode and O-2 at the anode is identified by analysing products from both electrodes. The results suggest that the cathodic current efficiency of electrolysis at 2 V is about 54.7%, energy consumption is about 5.27 kW h kg(-1) of Fe at 2 V electrolysis, and purity of the reduced Fe was more than 97 mol.%. With respect to the process temperature and product yield, B2O3-Na2O molten oxide has potential as a supporting electrolyte to reduce Fe2O3 to Fe without consuming any carbon.
- ISSN
- 0301-9233
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