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Charge-Transport Tuning of Solution-Processable Graphene Nanoribbons by Substitutional Nitrogen Doping

Cited 31 time in Web of Science Cited 34 time in Scopus
Authors
Kim, Kyung Tae; Lee, Jong Won; Jo, Won Ho
Issue Date
2013-12
Publisher
WILEY-VCH Verlag GmbH
Citation
Macromolecular Chemistry and Physics Vol.214 No.23, pp. 2768-2773
Keywords
공학graphene nanoribbonsnitrogen-dopingn-type semiconducting propertsolution processabilitythin-film transistors
Abstract
Novel nitrogen-doped graphene nanoribbons (GNR-Ns) are synthesized by the coupling reaction between a pyrazine (or benzene) derivative and naphthalene followed by cyclodehydrogenation. The amount of nitrogen doping in the GNR-Ns is controlled by changing the monomer feed ratio of pyrazine to benzene for polymerization. The electron mobility of the GNR-Ns increases while the hole mobility decreases, as the amount of nitrogen doping in the GNR increases, indicating that the charge-transport behavior of GNRs is changed from ambipolar to an n-type semiconductor. The threshold voltage of the GNR-Ns also shifts from 20 to ?6 V as the amount of nitrogen doping increases.
ISSN
1022-1352 (print)
1022-1352 (online)
Language
English
URI
https://hdl.handle.net/10371/91374
DOI
https://doi.org/10.1002/macp.201300529
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College of Engineering/Engineering Practice School (공과대학/대학원)Dept. of Material Science and Engineering (재료공학부) Journal Papers (저널논문_재료공학부)
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