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Rhodium-catalyzed reactions using alcohol as a carbon monoxide, nucleophile, hydration and alkylating source : 로듐촉매를 사용하여 알코올을 일산화탄소와 친핵체, 수화 및 알킬화 공급원으로 이용하는 반응 연구
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- Authors
- Advisor
- 정영근
- Major
- 자연과학대학 화학부
- Issue Date
- 2017-08
- Publisher
- 서울대학교 대학원
- Keywords
- rhodium ; ester ; alcohol ; alkyne ; carbonylation ; chiral ; α-alkylated ketone ; hydration ; alkylation ; addition reaction
- Description
- 학위논문 (석사)-- 서울대학교 대학원 자연과학대학 화학부, 2017. 8. 정영근.
- Abstract
- A CO-gas-free rhodium-catalyzed alkoxycarbonylation of aryl iodide with alcohols has been developed. Alcohols, with/without the aid of an aldehyde, were used as a carbon monoxide and nucleophile source.
Moreover, atom economic rhodium-catalyzed synthesis of chiral α-alkylated ketone from alkyne with benzyl alcohols has been developed. Benzyl alcohols were used as a hydration and alkylation source.
- Language
- English
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