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A Study on Thermal Insulation Performance of Electrospun Fiber Mat Laden with Nano/Micro Particles : 마이크로/나노입자가 혼입된 전기 방사 섬유 단열성능 연구

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dc.contributor.advisor이우일-
dc.contributor.author윤창기-
dc.date.accessioned2018-11-12T00:54:16Z-
dc.date.available2018-11-12T00:54:16Z-
dc.date.issued2018-08-
dc.identifier.other000000153158-
dc.identifier.urihttps://hdl.handle.net/10371/143017-
dc.description학위논문 (박사)-- 서울대학교 대학원 : 공과대학 기계항공공학부, 2018. 8. 이우일.-
dc.description.abstractAs the worldwide interest is focusing on the energy efficiency, the

insulation material and techniques which can reduce energy loss

become rising. One of the effective method is using super insulation

material.

Super insulation material is an insulation material whose thermal

conductivity is less than the air`s thermal conductivity (26mw/m∙K).

The aerogel panel and vacuum insulation panel are the most popular

super insulation material. Both materials have low thermal

conductivity, but they are too expensive and the manufacturing

process is complicate. Also the mechanical strength of materials is

bad for in daily life. To substitute the existing super insulation

material, we invested the new method for super insulation material

and manufacturing process.

ii

New material is made with electrospinning method which can make

micro-nano fiber with polymer. Using this polymer fiber as a bonding

material, we tried to make micro-nano particle based super

insulation material. The particles were glass hollow beads and silica

aerogel. Both particles have low density and thermal conductivity, so

they are used in many areas for insulation. The thermal conductivity

of made with the glass hollow bead was about 31 mw/m∙K, but the

silica aerogel had 22 mw/m∙K thermal conductivity.and, we tried

thinner fiber which made with NaCl, and the fiber mat without

particles had the 31 mw/m∙K.

As the new super insulation material is made with polymer, so it is

easy to burn. Therefore, the fire retardant used to protect the fibers

from the flame. The thermal conductivity of the film was influenced

little but when the fiber had the pores on the surface, the thermal

conductivity was decreased than before. Also the resultant of TGA

was increased.

The mechanical property was tested with tensile stress. As the mat

was made with fibers, so the all-round samples` tensile stress was

pretty low. In the case of NaCl added the value was increased, on the

other hand, when fire retardant added, the value was decreased

drastically.

Keywords : Electrospinning, micro-nano particle, Silica aerogel, PLA,

Thermal conductivity, fire retardant
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dc.description.tableofcontentsChapter 1. INTRODUCTION 1

1.1 Overview and problem description 1

1.2 Micro-nano scale particle and thermal insulation model . 7

1.2.1 Micro-nanoparticle 7

1.2.2 Knudsen effect 7

1.3 Research object . 10

Chapter 2. EXPERIMENT 12

2.1 Polymer . 12

2.1.1 Poly Lactic Acid (PLA) . 12

2.1.2 Ammonium Polyphosphate (APP) . 13

2.1.3 Preparation of polymer solution . 14

2.2 Process 15

2.2.1 Electrospinning 15

2.2.2 Metal pin 17

2.2.3 Motored sieve for suppling micro-nano particles. 18

2.2.4 Porous fiber 19

2.3 Measurement 22

2.3.1 Thermal conductivity 22

2.3.2 Thermal stability . 23

2.3.3 Tensile strength 24

2.3.4 Brunauer, Emmett and Teller (BET) Measurement 25

Chapter 3. PROPERTIES OF PLA FIBER/MICRONANOPARTICLE COMPOSITE MAT 27

3.1 shape change of fiber in relation to PLA concentration . 27

3.2 Comparison of insulation performance 32

3.3 Porous structure 33

3.4 Glass hollow beads . 35

3.5 Silica aerogel (SAG) . 41

3.6 Permanency of thermal insulation performance of fiber mat 45

3.7 Control of fiber thickness using NaCl 47

3.8 Flame retardancy of fiber mat using Ammonium polyphosphate 51

3.9 Tensile stress test of fiber mat 58

Chapter 4. PREDICTION SIMULATION OF THERMAL CONDUCTIVITY OF FIBER MAT 61

Chapter 5. CONCLUSION . 70

Reference . 73
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dc.language.isoen-
dc.publisher서울대학교 대학원-
dc.subject.ddc621-
dc.titleA Study on Thermal Insulation Performance of Electrospun Fiber Mat Laden with Nano/Micro Particles-
dc.title.alternative마이크로/나노입자가 혼입된 전기 방사 섬유 단열성능 연구-
dc.typeThesis-
dc.contributor.AlternativeAuthorChang Ki Yoon-
dc.description.degreeDoctor-
dc.contributor.affiliation공과대학 기계항공공학부-
dc.date.awarded2018-08-
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