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Formation of the Tertiary Sulfonamide C(sp(3))-N Bond Using Alkyl Boronic Ester via Intramolecular and Intermolecular Copper-Catalyzed Oxidative Cross-Coupling
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Dong Sun | - |
dc.contributor.author | Lee, Hong Geun | - |
dc.date.accessioned | 2022-05-04T01:45:43Z | - |
dc.date.available | 2022-05-04T01:45:43Z | - |
dc.date.created | 2022-03-08 | - |
dc.date.issued | 2021-12 | - |
dc.identifier.citation | Journal of Organic Chemistry, Vol.86 No.23, pp.17380-17394 | - |
dc.identifier.issn | 0022-3263 | - |
dc.identifier.uri | https://hdl.handle.net/10371/179381 | - |
dc.description.abstract | A synthetic strategy for the formation of C(sp(3))-N bonds, particularly through a copper-catalyzed oxidative cross-coupling, is rare. Herein, we report a novel synthetic approach for the preparation of tertiary sulfonamides via copper-catalyzed intra-and intermolecular oxidative C(sp(3))-N cross-coupling reactions. This method allows the utilization of the readily available C(sp(3))-based pinacol boronate as a substrate and the tolerance of a wide range of functional groups under mild reaction conditions. The success of this strategy relies on the unprecedented additive effects of silanol and NaIO4 . | - |
dc.language | 영어 | - |
dc.publisher | American Chemical Society | - |
dc.title | Formation of the Tertiary Sulfonamide C(sp(3))-N Bond Using Alkyl Boronic Ester via Intramolecular and Intermolecular Copper-Catalyzed Oxidative Cross-Coupling | - |
dc.type | Article | - |
dc.identifier.doi | 10.1021/acs.joc.1c01759 | - |
dc.citation.journaltitle | Journal of Organic Chemistry | - |
dc.identifier.wosid | 000752848600099 | - |
dc.identifier.scopusid | 2-s2.0-85119409484 | - |
dc.citation.endpage | 17394 | - |
dc.citation.number | 23 | - |
dc.citation.startpage | 17380 | - |
dc.citation.volume | 86 | - |
dc.description.isOpenAccess | N | - |
dc.contributor.affiliatedAuthor | Lee, Hong Geun | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
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