Publications
Detailed Information
A Unified Synthetic Strategy to Introduce Heteroatoms via Electrochemical Functionalization of Alkyl Organoboron Reagents
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Go, Su Yong | - |
dc.contributor.author | Chung, Hyunho | - |
dc.contributor.author | Shin, Samuel Jaeho | - |
dc.contributor.author | An, Sohee | - |
dc.contributor.author | Youn, Ju Hyun | - |
dc.contributor.author | Im, Tae Yeong | - |
dc.contributor.author | Kim, Ji Yong | - |
dc.contributor.author | Chung, Taek Dong | - |
dc.contributor.author | Lee, Hong Geun | - |
dc.date.accessioned | 2022-09-30T05:49:50Z | - |
dc.date.available | 2022-09-30T05:49:50Z | - |
dc.date.created | 2022-06-20 | - |
dc.date.issued | 2022-05 | - |
dc.identifier.citation | Journal of the American Chemical Society, Vol.144 No.20, pp.9149-9160 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | https://hdl.handle.net/10371/184825 | - |
dc.description.abstract | Based on systematic electrochemical analysis, an integrated synthetic platform of C(sp3)-based organoboroncompounds was established for the introduction of heteroatoms. The electrochemically mediated bond-forming strategy was shownto be highly effective for the functionalization of sp3-hybridized carbon atoms with significant steric hindrance. Moreover, virtually allthe nonmetallic heteroatoms could be utilized as reaction partners using one unified protocol. The observed reactivity stems fromthe two consecutive single-electron oxidations of the substrate, which eventually generates an extremely reactive carbocation as thekey intermediate. The detailed reaction profile could be elucidated through multifaceted electrochemical studies. Ultimately, a newdimension in the activation strategies for organoboron compounds was accomplished through the electrochemically driven reactiondevelopment | - |
dc.language | 영어 | - |
dc.publisher | American Chemical Society | - |
dc.title | A Unified Synthetic Strategy to Introduce Heteroatoms via Electrochemical Functionalization of Alkyl Organoboron Reagents | - |
dc.type | Article | - |
dc.identifier.doi | 10.1021/jacs.2c03213 | - |
dc.citation.journaltitle | Journal of the American Chemical Society | - |
dc.identifier.wosid | 000805981500033 | - |
dc.identifier.scopusid | 2-s2.0-85131019014 | - |
dc.citation.endpage | 9160 | - |
dc.citation.number | 20 | - |
dc.citation.startpage | 9149 | - |
dc.citation.volume | 144 | - |
dc.description.isOpenAccess | N | - |
dc.contributor.affiliatedAuthor | Chung, Hyunho | - |
dc.contributor.affiliatedAuthor | Chung, Taek Dong | - |
dc.contributor.affiliatedAuthor | Lee, Hong Geun | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
- Appears in Collections:
- Files in This Item:
- There are no files associated with this item.
Item View & Download Count
Items in S-Space are protected by copyright, with all rights reserved, unless otherwise indicated.