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Structure of a subnanometer-sized semiconductor Cd14Se13 cluster
DC Field | Value | Language |
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dc.contributor.author | Bootharaju, Megalamane S. | - |
dc.contributor.author | Baek, Woonhyuk | - |
dc.contributor.author | Deng, Guocheng | - |
dc.contributor.author | Singh, Kamalpreet | - |
dc.contributor.author | Voznyy, Oleksandr | - |
dc.contributor.author | Zheng, Nanfeng | - |
dc.contributor.author | Hyeon, Taeghwan | - |
dc.date.accessioned | 2023-03-20T08:36:45Z | - |
dc.date.available | 2023-03-20T08:36:45Z | - |
dc.date.created | 2023-03-14 | - |
dc.date.created | 2023-03-14 | - |
dc.date.created | 2023-03-14 | - |
dc.date.created | 2023-03-14 | - |
dc.date.created | 2023-03-14 | - |
dc.date.created | 2023-03-14 | - |
dc.date.issued | 2022-11 | - |
dc.identifier.citation | CHEM, Vol.8 No.11, pp.2978-2989 | - |
dc.identifier.issn | 2451-9308 | - |
dc.identifier.uri | https://hdl.handle.net/10371/189416 | - |
dc.description.abstract | Atomic-level structure characterization is central to the science and engineering of materials. However, the crystal structure determina-tion of magic-sized nanoclusters (MSCs), typical nuclei of the semi-conductor nanocrystals, is impeded by challenges in obtaining phase-pure MSCs. Herein, we report on the synthesis and X-ray crys-tal structure of -0.9-nanometer-sized 27-atom semiconductor MSC, Cd14Se13. Its structure has a central Se atom encapsulated by a Cd14Se12 cage with an adamantane-like CdSe arrangement. Two chloride ions released in situ from the dichloromethane solvent sta-bilize and linearly self-assemble the clusters. The formation and growth pathways of Cd14Se13 clusters provide vital insights into the size-structure-property relationships in MSCs. Furthermore, po-tential sites for magnetic dopants are identified in Cd14Se13 MSC, enabling research on atomically precise dilute magnetic semicon-ductors. | - |
dc.language | 영어 | - |
dc.publisher | CELL PRESS | - |
dc.title | Structure of a subnanometer-sized semiconductor Cd14Se13 cluster | - |
dc.type | Article | - |
dc.identifier.doi | 10.1016/j.chempr.2022.06.025 | - |
dc.citation.journaltitle | CHEM | - |
dc.identifier.wosid | 000922735600014 | - |
dc.identifier.scopusid | 2-s2.0-85136772197 | - |
dc.citation.endpage | 2989 | - |
dc.citation.number | 11 | - |
dc.citation.startpage | 2978 | - |
dc.citation.volume | 8 | - |
dc.description.isOpenAccess | Y | - |
dc.contributor.affiliatedAuthor | Hyeon, Taeghwan | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.subject.keywordPlus | COLLOIDAL QUANTUM DOTS | - |
dc.subject.keywordPlus | REVERSIBLE ISOMERIZATION | - |
dc.subject.keywordPlus | OPTICAL-PROPERTIES | - |
dc.subject.keywordPlus | CDSE NANOCLUSTERS | - |
dc.subject.keywordPlus | NANOCRYSTALS | - |
dc.subject.keywordPlus | GROWTH | - |
dc.subject.keywordPlus | TRANSFORMATIONS | - |
dc.subject.keywordPlus | INTERFACE | - |
dc.subject.keywordPlus | CRYSTAL | - |
dc.subject.keywordAuthor | Cd14Se13 clusters | - |
dc.subject.keywordAuthor | Cd34Se33 clusters | - |
dc.subject.keywordAuthor | colloidal semiconductors | - |
dc.subject.keywordAuthor | dilute magnetic semiconductors | - |
dc.subject.keywordAuthor | ligand exchange | - |
dc.subject.keywordAuthor | magic-sized clusters | - |
dc.subject.keywordAuthor | Other | - |
dc.subject.keywordAuthor | photoluminescence | - |
dc.subject.keywordAuthor | SDG7: Affordable and clean energy | - |
dc.subject.keywordAuthor | size conversion | - |
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