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Orthogonal Reactivity of Acyl Azides in C–H Activation: Dichotomy between C–C and C–N Amidations Based on Catalyst Systems : Orthogonal Reactivity of Acyl Azides in C-H Activation: Dichotomy between C-C and C-N Amidations Based on Catalyst Systems
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Shin, Kwangmin | - |
| dc.contributor.author | Ryu, Jaeyune | - |
| dc.contributor.author | Chang, Sukbok | - |
| dc.date.accessioned | 2023-05-03T05:46:54Z | - |
| dc.date.available | 2023-05-03T05:46:54Z | - |
| dc.date.created | 2023-05-01 | - |
| dc.date.created | 2023-05-01 | - |
| dc.date.created | 2023-05-01 | - |
| dc.date.created | 2023-05-01 | - |
| dc.date.created | 2023-05-01 | - |
| dc.date.issued | 2014-04 | - |
| dc.identifier.citation | Organic Letters, Vol.16 No.7, pp.2022-2025 | - |
| dc.identifier.issn | 1523-7060 | - |
| dc.identifier.uri | https://hdl.handle.net/10371/191819 | - |
| dc.description.abstract | The dual reactivity of acyl azides was utilized successfully in C-H activation by the choice of catalyst systems: while selective C-C amidation was achieved under thermal Rh catalysis, a Ru catalyst was found to mediate direct C-N amidation also highly selectively. Investigations of the mechanistic dichotomy between two catalytic systems are also presented. | - |
| dc.language | 영어 | - |
| dc.publisher | American Chemical Society | - |
| dc.title | Orthogonal Reactivity of Acyl Azides in C–H Activation: Dichotomy between C–C and C–N Amidations Based on Catalyst Systems | - |
| dc.title.alternative | Orthogonal Reactivity of Acyl Azides in C-H Activation: Dichotomy between C-C and C-N Amidations Based on Catalyst Systems | - |
| dc.type | Article | - |
| dc.identifier.doi | 10.1021/ol500602b | - |
| dc.citation.journaltitle | Organic Letters | - |
| dc.identifier.wosid | 000334016600049 | - |
| dc.identifier.scopusid | 2-s2.0-84898716383 | - |
| dc.citation.endpage | 2025 | - |
| dc.citation.number | 7 | - |
| dc.citation.startpage | 2022 | - |
| dc.citation.volume | 16 | - |
| dc.description.isOpenAccess | N | - |
| dc.contributor.affiliatedAuthor | Ryu, Jaeyune | - |
| dc.type.docType | Article | - |
| dc.description.journalClass | 1 | - |
| dc.subject.keywordPlus | BOND ACTIVATION | - |
| dc.subject.keywordPlus | CONVERGENT SYNTHESIS | - |
| dc.subject.keywordPlus | DIRECT ARYLATIONS | - |
| dc.subject.keywordPlus | ARYL AZIDES | - |
| dc.subject.keywordPlus | RHODIUM | - |
| dc.subject.keywordPlus | AMINATION | - |
| dc.subject.keywordPlus | ARENES | - |
| dc.subject.keywordPlus | FUNCTIONALIZATION | - |
| dc.subject.keywordPlus | COMPLEXES | - |
| dc.subject.keywordPlus | ISOCYANATES | - |
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Related Researcher
- Ryu, Jaeyune류재윤
- 조교수
- College of Engineering
- School of Chemical and Biological Engineering
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