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Defects on the surface of Ti-doped MgAl2O4 nanophosphor

Cited 2 time in Web of Science Cited 3 time in Scopus
Authors

Lim, Jaehyuk; Kim, Yongseon; Kim, Sungdae; Kim, Youngwoon; Kang, Shinhoo

Issue Date
2017-09
Publisher
Springer Verlag
Citation
Nanoscale Research Letters, Vol.12, p. 536
Abstract
Ti-doped nano MgAl2O4 for white emission was synthesized by combustion method. Extrinsic Schottky defects, Al vacancies and Ti4+ dopant in Al sites, which are considered to be responsible for bluish-white emission, were observed by STEM on the surface of Ti-doped nano MgAl2O4 powder. The stabilities of the Schottky defect associates, (Ti-Al-V'''(Al))'', were demonstrated by DFT calculation. The emission behavior was interpreted with these results.
ISSN
1931-7573
URI
https://hdl.handle.net/10371/197638
DOI
https://doi.org/10.1186/s11671-017-2288-1
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