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Orthogonal Dual Photocatalysis of Single Atoms on Carbon Nitrides for One-Pot Relay Organic Transformation
DC Field | Value | Language |
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dc.contributor.author | Kim, Sumin | - |
dc.contributor.author | Bok, Jinsol | - |
dc.contributor.author | Lee, Byoung-Hoon | - |
dc.contributor.author | Choi, Hyunwoo | - |
dc.contributor.author | Seo, Youngran | - |
dc.contributor.author | Kim, Jiheon | - |
dc.contributor.author | Kim, Junhee | - |
dc.contributor.author | Ko, Wonjae | - |
dc.contributor.author | Lee, Kug-Seung | - |
dc.contributor.author | Cho, Sung-Pyo | - |
dc.contributor.author | Hyeon, Taeghwan | - |
dc.contributor.author | Yoo, Dongwon | - |
dc.date.accessioned | 2024-01-04T08:01:13Z | - |
dc.date.available | 2024-01-04T08:01:13Z | - |
dc.date.created | 2023-12-05 | - |
dc.date.issued | 2023-10 | - |
dc.identifier.citation | ACS Nano, Vol.17 No.21, pp.21470-21479 | - |
dc.identifier.issn | 1936-0851 | - |
dc.identifier.uri | https://hdl.handle.net/10371/198792 | - |
dc.description.abstract | Single-atom photocatalysis has shown potential in various single-step organic transformations, but its use in multistep organic transformations in one reaction systems has rarely been achieved. Herein, we demonstrate atomic site orthogonality in the M-1/C3N4 system (where M = Pd or Ni), enabling a cascade photoredox reaction involving oxidative and reductive reactions in a single system. The system utilizes visible-light-generated holes and electrons from C3N4, driving redox reactions (e.g., oxidation and fluorination) at the surface of C3N4 and facilitating cross-coupling reactions (e.g., C-C and C-O bond formation) at the metal site. The concept is generalized to different systems of Pd and Ni, thus making the catalytic site-orthogonal M-1/C3N4 system an ideal photocatalyst for improving the efficiency and selectivity of multistep organic transformations. | - |
dc.language | 영어 | - |
dc.publisher | American Chemical Society | - |
dc.title | Orthogonal Dual Photocatalysis of Single Atoms on Carbon Nitrides for One-Pot Relay Organic Transformation | - |
dc.type | Article | - |
dc.identifier.doi | 10.1021/acsnano.3c06314 | - |
dc.citation.journaltitle | ACS Nano | - |
dc.identifier.wosid | 001105129900001 | - |
dc.identifier.scopusid | 2-s2.0-85177103027 | - |
dc.citation.endpage | 21479 | - |
dc.citation.number | 21 | - |
dc.citation.startpage | 21470 | - |
dc.citation.volume | 17 | - |
dc.description.isOpenAccess | N | - |
dc.contributor.affiliatedAuthor | Hyeon, Taeghwan | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.subject.keywordPlus | PHOTOREDOX CATALYSIS | - |
dc.subject.keywordPlus | FLUORINE | - |
dc.subject.keywordPlus | COBALT | - |
dc.subject.keywordPlus | CO2 | - |
dc.subject.keywordAuthor | Photocatalysis | - |
dc.subject.keywordAuthor | Heterogeneous catalysis | - |
dc.subject.keywordAuthor | Single-atomcatalysis | - |
dc.subject.keywordAuthor | One-pot catalysis | - |
dc.subject.keywordAuthor | Carbon nitride | - |
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