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An improved catalyst system for the Pd-catalyzed fluorination of (hetero)aryl triflates
Cited 97 time in
Web of Science
Cited 105 time in Scopus
- Authors
- Issue Date
- 2013-11
- Publisher
- American Chemical Society
- Citation
- Organic Letters, Vol.15 No.21, pp.5602-5605
- Abstract
- The stable Pd(0) species [(1,5-cyclooctadiene)(L·Pd)2] (L = AdBrettPhos) has been prepared and successfully evaluated as a precatalyst for the fluorination of aryl triflates derived from biologically active and heteroaryl phenols, challenging substrates for our previously reported catalyst system. Additionally, this precatalyst activates at room temperature under neutral conditions, generates 1,5-cyclooctadiene as the only byproduct, and leads to overall cleaner reaction profiles. © 2013 American Chemical Society.
- ISSN
- 1523-7060
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