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(Bipyridyl-kappa N-2,N ')bis(eta(5)-pentamethylcyclopentadienyl) (trifluoromethane-sulfonato-kappa O)cerium(III) : (Bipyridyl-[kappa]2N,N')bis([eta]5-pentamethylcyclopentadienyl)(trifluoromethanesulfonato-[kappa]O)cerium(III)
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- Authors
- Issue Date
- 2007-06
- Publisher
- Blackwell Publishing Inc.
- Citation
- Acta Crystallographica Section E: Structure Reports Online, Vol.63 No.6, pp.M1656-U774
- Abstract
- The title compound, [ Ce( CF3SO3)( C10H15) (2)( C10H8N2)], crystallizes as a bent metallocene with an inner- sphere trifluoromethanesulfonate ligand [ Cg1 - Ce - Cg2 = 138.91 ( 1) A; Cg1 and Cg2 are the centroids of the cyclopentadienyl rings]. The pentamethylcyclopentadienyl rings have a slightly staggered conformation. The bipyridine ligand has an N - C - C - N torsion angle of - 8.2 ( 7)degrees.
- ISSN
- 1600-5368
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