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Preparation of anthracene-labelled poly(methyl methacrylate) via atom transfer radical polymerization

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Authors
Kim, Chi S.; Oh, Seung M.; Kim, Sejung; Cho, Chang G.
Issue Date
1998-12-16
Publisher
John Wiley & Sons
Citation
Macromol. Rapid Commun. 19, 191 (1998)
Abstract
Anthracene-labelled poly(methyl methacrylate) (PMMA) was prepared via atom transfer radical polymerization (ATRP) where 9,10-bis(chloromethyl)anthracene and CuCl/2,2'-bipyridine were used as the initiator and catalyst, respectively. Both the linear increase of the number average molecular mass with conversion and the narrow polydispersity in the resulting polymers suggest that the polymerization proceeds in a "living" fashion and the anthracene molecule is incorporated into the middle of the polymer backbone. The initiation efficiency was low, ca. 13%, presumably due to some side reactions which compete with the initiation reaction.
ISSN
1022-1336 (print)
1521-3927 (online)
Language
English
URI
http://www3.interscience.wiley.com/journal/10003314/abstract

http://hdl.handle.net/10371/5708
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College of Engineering/Engineering Practice School (공과대학/대학원)Dept. of Chemical and Biological Engineering (화학생물공학부)Journal Papers (저널논문_화학생물공학부)
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