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Semiflexible Polymer Brushes: Most Probable Configuration Approach Based on Cotinuous Chain Model

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Authors
Kim, Gwang Gyu; Char, Kookheon
Issue Date
1999
Publisher
대한화학회 = The Korean Chemical Society
Citation
Bull. Korean Chem. Soc. 1999, 20, 1026
Abstract
The properties of semiflexible polymer brushes are studied by applying the classical limit of mean-field approach for chains with marginal chain stiffness. Using the mean-spherical Gaussian model, the most probable configuration for semiflexible chains is obtained, which reduces to the parabolic brush of Milner et al. [Mac-romolecules 1988, 21, 2610] in the flexible limit. From this configuration, equilibrium brush height as well as interactions between semiflexible brushes are estimated.
ISSN
0253-2964
Language
English
URI
http://newjournal.kcsnet.or.kr/main/j_search/j_abstract_view.htm?code=B990911&qpage=j_search&spage=b_jkcs&dpage=ar

http://hdl.handle.net/10371/5912
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College of Engineering/Engineering Practice School (공과대학/대학원)Dept. of Chemical and Biological Engineering (화학생물공학부)Journal Papers (저널논문_화학생물공학부)
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