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Disk-type porous Ni–Cr bulk catalyst for hydrogen production by autothermal reforming of methane

Cited 9 time in Web of Science Cited 9 time in Scopus
Authors
Kim, Sung Ho; Chung, Ji Hye; Kim, Yun Tae; Han, Jonghee; Yoon, Sung Pil; Nam, Suk-Woo; Lim, Tae-Hoon; Lee, Ho-In
Issue Date
2009
Publisher
Elsevier
Citation
Catalysis Today 146 (2009) 96–102
Keywords
Disk-type catalystNi bulk catalystATRMethane reformingOn–Off test
Abstract
Autothermal reforming of methane, which is combined of steam reforming and partial oxidation, was
carried out with a disk-type porous Ni–Cr bulk catalyst in various reaction conditions. Although high
methane conversion could be obtained by controlling reaction conditions such as reaction temperature,
O2/C ratio, and S/C ratio, the optimal condition for maximal H2 and CO generation was shown at a
different reaction condition, because H2 and CO were products of partially oxidized methane. The
activity of porous Ni–Cr bulk catalyst was well maintained for On–Off test and 260 h operation of ATR.
The deactivation of a reforming catalyst has generally been caused by the carbon deposition on the active
site of Ni. In the case of bulk Ni, however, the oxidation of Ni was an inevitable and severe problem in the
autothermal reforming of methane. An interesting fact was observed during On–Off test, which was
named a bounce phenomenon in this work. It was caused by oxidation of Ni for On–Off process and the
transient reduction of the oxidized Ni catalyst in ATR reaction.
ISSN
0920-5861
Language
English
URI
http://hdl.handle.net/10371/61280
DOI
https://doi.org/10.1016/j.cattod.2009.01.042
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College of Engineering/Engineering Practice School (공과대학/대학원)Dept. of Chemical and Biological Engineering (화학생물공학부)Journal Papers (저널논문_화학생물공학부)
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