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Parallel and vertical morphologies in block copolymers of cylindrical domain
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- Authors
- Issue Date
- 1998-01-15
- Publisher
- American Institute of Physics
- Citation
- J. Chem. Phys. 108, 1253 (1998)
- Keywords
- DIBLOCK COPOLYMERS ; NEUTRON REFLECTIVITY ; THIN-FILMS ; PHASE ; MELTS
- Abstract
- We present a theoretical result on the ordering of cylindrical morphology in diblock and triblock copolymers. The equilibrium morphology of A-B diblock and A-B-A triblock copolymer films is shown to have the cylinders oriented parallel or vertical to the surface, depending on the film thickness and surface tensions. A criterion is derived that can be used to determine the conditions under which the orientation is parallel or vertical.
- ISSN
- 0021-9606
- Language
- English
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