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Synthesis and Photovoltaic Properties of Benzothiadiazole-Based Copolymer Containing Fluorinated Benzene as Weak Electron Donating Unit for Polymer Solar Cells
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 이진용 | - |
dc.contributor.author | 조제웅 | - |
dc.contributor.author | 조원호 | - |
dc.creator | 조원호 | - |
dc.date.accessioned | 2014-05-09T02:19:26Z | - |
dc.date.available | 2014-05-09T02:19:26Z | - |
dc.date.issued | 2014-04-09 | - |
dc.identifier.citation | 한국고분자학회 2014 춘계학술대회, 대전컨벤션센터, p. 138 | - |
dc.identifier.uri | https://hdl.handle.net/10371/91718 | - |
dc.description.abstract | 1,4-Di(thiophene-2-yl)benzene (DTB), which is a phenyl compound flanked with thiophene, was synthesized via a simple synthetic route and utilized as a weak electron-donating unit in D?A type copolymer for lowering the HOMO of the copolymer. A copolymer (PDTBDTBT) was synthesized by reacting DTB with 4,7-di(thiophen-2-yl)benzo[c][1,2,5]thiadiazole (DTBT). Fluorination of benzene moiety between thiophenes (F2DTB) was carried out for further lowering the HOMO energy level of the copolymer due to the strong electron-withdrawing property of fluorine. When the F2DTB is used as an electron-rich unit for conjugated copolymers (PF2DTBDTBT) which exhibits a deep HOMO energy level of ?5.5 eV, the PSCs fabricated from PFDTBDTBT exhibit a high VOC, leading to a promising PCE. | en |
dc.language.iso | en | en |
dc.publisher | 한국고분자학회 | en |
dc.subject | 공학 | en |
dc.title | Synthesis and Photovoltaic Properties of Benzothiadiazole-Based Copolymer Containing Fluorinated Benzene as Weak Electron Donating Unit for Polymer Solar Cells | en |
dc.type | Conference Paper | - |
dc.description.srnd | OAIID:oai:osos.snu.ac.kr:snu2014-01/104/0000001236/3 | - |
dc.description.srnd | SEQ:3 | - |
dc.description.srnd | PERF_CD:SNU2014-01 | - |
dc.description.srnd | EVAL_ITEM_CD:104 | - |
dc.description.srnd | USER_ID:0000001236 | - |
dc.description.srnd | ADJUST_YN:N | - |
dc.description.srnd | EMP_ID:A004558 | - |
dc.description.srnd | DEPT_CD:445 | - |
dc.description.srnd | CITE_RATE:0 | - |
dc.description.srnd | FILENAME:2014춘계고분자학회_이진용.pdf | - |
dc.description.srnd | DEPT_NM:재료공학부 | - |
dc.description.srnd | CONFIRM:Y | - |
dc.identifier.srnd | 2014-01/104/0000001236/3 | - |
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