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A new Mg-ion intercalation host of LiNi0.5Co0.2Mn0.3O2 as cathode materials for rechargeable Mg batteries : 마그네슘이차전지용 마그네슘 이온 삽입이 가능한 새로운 구조의 LiNi0.5Co0.2Mn0.3O2 양극 소재 연구
DC Field | Value | Language |
---|---|---|
dc.contributor.advisor | 강기석 | - |
dc.contributor.author | 조용범 | - |
dc.date.accessioned | 2017-07-14T03:13:03Z | - |
dc.date.available | 2017-07-14T03:13:03Z | - |
dc.date.issued | 2016-08 | - |
dc.identifier.other | 000000135927 | - |
dc.identifier.uri | https://hdl.handle.net/10371/123379 | - |
dc.description | 학위논문 (석사)-- 서울대학교 대학원 : 재료공학부, 2016. 8. 강기석. | - |
dc.description.abstract | Mg rechargeable battery is one of the most promising next-generation batteries on the merits of its high theoretical capacity, low cost and safety. However, searching new cathode materials with high energy density has been a great challenge so far due to the sluggish diffusion kinetics of divalent Mg2+ ions in the crystal structure of electrode materials. In this study, we utilize LiNi0.5Co0.2Mn0.3O2 (NCM523), which is widely used electrode material for Li-ion batteries (LIBs), as a cathode material for Mg rechargeable battery. We first discover that NCM523 can be a Mg intercalation host with high energy density along with the water-induced phase transformation from O3 to P3 layered structure. The water-intercalated P3 phase delivers the highest Ni2+/Ni3+/Ni4+ redox potential of 3.1 V vs. Mg/Mg2+ yet reported for Mg cathode materials, with high energy density of 589 Wh kg-1. This unusual behavior in NCM layered oxide, proposed in this work, provides an insight into designing promising cathode materials for Mg rechargeable battery. | - |
dc.description.tableofcontents | Chapter 1. Introduction 1
1.1 Motivation and outline 1 Chapter 2. Reaserch backgrounds 4 2.1. Introduction to Mg rechargeable batteries 4 2.2. Layered oxide 5 Chapter 3. Experimental 8 3.1. Characterization of LiNi0.5Co0.2Mn0.3O2 8 3.2. Electrochemical analysis 8 3.3. Ex-situ structural analysis 9 3.3.1. X-ray diffraction 9 3.3.2. High-Resolution transmission electron microscope 9 3.3.3. Fourier transform infrared spectrometry 10 3.3.4. Thermal gravimetric analysis 10 3.3.5. X-ray photoelectron spectroscopy 11 3.3.6. Field-Emission scanning electron microscopy 11 3.3.7. X-ray absorption spectroscopy 11 Chapter 4. Results and discussion 13 4.1. Effect of charge capacity on electrochemical activity 13 4.2. Activation process and de/magnesiation mechanism 17 4.3. Confirmation of de/magnesiation 30 4.4. Monitoring redox reaction of Ni, Co and Mn 33 Chapter 5. Conclusion 37 Reference 38 국문 요약 47 | - |
dc.format | application/pdf | - |
dc.format.extent | 1526012 bytes | - |
dc.format.medium | application/pdf | - |
dc.language.iso | ko | - |
dc.publisher | 서울대학교 대학원 | - |
dc.subject | 마그네슘 이차 전지 | - |
dc.subject | 층상형 산화물 | - |
dc.subject | P3상 | - |
dc.subject | 물 | - |
dc.subject | 마그네시에이션 | - |
dc.subject.ddc | 620 | - |
dc.title | A new Mg-ion intercalation host of LiNi0.5Co0.2Mn0.3O2 as cathode materials for rechargeable Mg batteries | - |
dc.title.alternative | 마그네슘이차전지용 마그네슘 이온 삽입이 가능한 새로운 구조의 LiNi0.5Co0.2Mn0.3O2 양극 소재 연구 | - |
dc.type | Thesis | - |
dc.contributor.AlternativeAuthor | Cho, Yongbeom | - |
dc.description.degree | Master | - |
dc.citation.pages | 48 | - |
dc.contributor.affiliation | 공과대학 재료공학부 | - |
dc.date.awarded | 2016-08 | - |
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