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Designed synthesis of SiO2/TiO2 core/shell structure as light scattering material for highly efficient dye-sensitized solar cells

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dc.contributor.advisor장정식-
dc.contributor.author손수임-
dc.date.accessioned2017-07-19T06:00:34Z-
dc.date.available2017-07-19T06:00:34Z-
dc.date.issued2013-02-
dc.identifier.other000000010273-
dc.identifier.urihttps://hdl.handle.net/10371/129465-
dc.description학위논문 (석사)-- 서울대학교 대학원 : 화학생물공학부, 2013. 2. 장정식.-
dc.description.abstractSiO2/TiO2 core/shell nanoparticles (STCS-NPs) with diameters of 110, 240, 530 nm were fabricated to investigate the influence of the size and refractive index of light-scattering particles on light-scattering properties. The optical properties of STCS-NPs were evaluated and compared with SiO2-NPs and TiO2-NPs. Considering the size effect, the reflectance gets higher with increasing size of NPs. Also, it was shown that the structure of the STCS-NPs, consisting of a low refractive index core and high refractive index shell, contributed to the high scattering efficiency.The dye-sensitized solar cell (DSSC) containing STCS-NPs exhibited an enhanced power conversion efficiency (PCE) of 20 % compared with the pristine DSSC.-
dc.description.tableofcontentsChapter 1 Introduction 1
1.1 Dye-sensitized solar cells 1
1.2 Light-scattering nanostructures 4
1.2.1 Light-scattering materials 4
1.2.2 Light-scattering theory 5
1.2.3 Core/shell nanoparticles 6
1.3 Characteristics of SiO2 and TiO2 7
1.3.1 SiO2 7
1.3.2 TiO2 8
1.4 Objective of this study 10
Chapter 2 Experimental 12
2.1 Preparation of SiO2, TiO2, STCS NPs 12
2.1.1 SiO2-NPs 12
2.1.2 TiO2-NPs 13
2.1.3 STCS-NPs 14
2.2 Solar cell preparation 15
2.3 Characterization 16
Chapter 3 Results and discussion 17
3.1 Fabrication and microscopic observation of the STCS-NPs 17
3.2 Optical property analysis 25
3.3 Photovoltaic performance of DSSCs 32
Chapter 4 Conclusion 45
References 47
Abstract 52
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dc.formatapplication/pdf-
dc.format.extent27557010 bytes-
dc.format.mediumapplication/pdf-
dc.language.isoen-
dc.publisher서울대학교 대학원-
dc.subject.ddc660-
dc.titleDesigned synthesis of SiO2/TiO2 core/shell structure as light scattering material for highly efficient dye-sensitized solar cells-
dc.typeThesis-
dc.contributor.AlternativeAuthorSuim Son-
dc.description.degreeMaster-
dc.citation.pagesviii, 53-
dc.contributor.affiliation공과대학 화학생물공학부(에너지환경 화학융합기술전공)-
dc.date.awarded2013-02-
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