Publications
Detailed Information
Well-dispersed sulfur wrapped in reduced graphene oxide nanoscroll as cathode material for lithium-sulfur battery : 양극소재 황-그래핀 나노스크롤 복합체의 합성과 고용량 리튬황전지에의 응용
DC Field | Value | Language |
---|---|---|
dc.contributor.advisor | 박원철 | - |
dc.contributor.author | 유수연 | - |
dc.date.accessioned | 2017-07-19T10:57:13Z | - |
dc.date.available | 2017-07-19T10:57:13Z | - |
dc.date.issued | 2016-08 | - |
dc.identifier.other | 000000135950 | - |
dc.identifier.uri | https://hdl.handle.net/10371/133214 | - |
dc.description | 학위논문 (석사)-- 서울대학교 융합과학기술대학원 : 융합과학부, 2016. 8. 박원철. | - |
dc.description.abstract | For large scale batteries, sulfur is an attractive cathode active material for lithium batteries because of high theoretical capacity of 1675 mA h g-1. However, severe capacity fading and low conductivity of sulfur are significant challenges for its practical application. Here, we report a facile approach to prepare reduced graphene oxide nanoscroll embedded with well-dispersed sulfur (S/GNSC) through a one-pot oxidation of sulfide and reduction of graphene oxide followed by freeze-casting process to generate graphene nanoscroll. The S/GNSC takes the novel shape of reduced graphene oxid sheet spirally wrapped into one-dimensional tubular structure, which enhances electrochemical performance by acting as physical barrier to prevent polysulfide from dissolving and an effective network to promote electron and Li+ transport during reaction. Therefore, the S/GNSC composite with high sulfur loading of 76 wt% exhibits high initial capacity of 1295 mA h g-1 and reversible capacity of 744 mA h g-1 after the 100th cycle at 0.2 C when it is used as a cathode material for lithium-sulfur battery, while the capacity of sulfur loaded on reduced graphene oxide sheet (S/rGO) is continuously fading to 510 mA h g-1 after the 100th cycle due to the irreversible loss of polysulfide. | - |
dc.description.tableofcontents | 1. Introduction 1
1.1 Lithium-sulfur battery 2 1.2 Sulfur and carbon composite 3 1.3 Graphene nanoscroll 4 2. Experimental 7 2.1 Materials 7 2.2 Synthesis of graphene oxides 7 2.3 Synthesis of sulfur/reduced graphene oxide composite 8 2.4 Synthesis of sulfur/reduced graphene oxide nanoscroll composite 9 2.5 Structural and morphological characterizations 9 2.6 Electrochemical characterizations 10 3. Result and Discussion 12 3.1 Structural and morphological characterization 12 3.2 Electrochemical characterization 31 4. Conclusion 42 References 43 국문 초록 49 | - |
dc.format | application/pdf | - |
dc.format.extent | 2203444 bytes | - |
dc.format.medium | application/pdf | - |
dc.language.iso | en | - |
dc.publisher | 서울대학교 융합과학기술대학원 | - |
dc.subject | Lithium-sulfur battery | - |
dc.subject | cathode | - |
dc.subject | reduced graphene oxide | - |
dc.subject | graphene scroll | - |
dc.subject | porous carbon structure | - |
dc.subject.ddc | 620 | - |
dc.title | Well-dispersed sulfur wrapped in reduced graphene oxide nanoscroll as cathode material for lithium-sulfur battery | - |
dc.title.alternative | 양극소재 황-그래핀 나노스크롤 복합체의 합성과 고용량 리튬황전지에의 응용 | - |
dc.type | Thesis | - |
dc.description.degree | Master | - |
dc.citation.pages | ⅷ, 50 | - |
dc.contributor.affiliation | 융합과학기술대학원 융합과학부 | - |
dc.date.awarded | 2016-08 | - |
- Appears in Collections:
- Files in This Item:
Item View & Download Count
Items in S-Space are protected by copyright, with all rights reserved, unless otherwise indicated.