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Solar energy conversion by the regular array of TiO2 nanotubes anchored with ZnS/CdSSe/CdS quantum dots formed by sequential ionic bath deposition : TiO2나노튜브에 SILAR방법으로 ZnS/CdSSe/CdS양자점을 도입한 태양전지 연구
DC Field | Value | Language |
---|---|---|
dc.contributor.advisor | 이성훈 | - |
dc.contributor.author | 박수정 | - |
dc.date.accessioned | 2017-07-19T11:01:53Z | - |
dc.date.available | 2017-07-19T11:01:53Z | - |
dc.date.issued | 2013-02 | - |
dc.identifier.other | 000000008919 | - |
dc.identifier.uri | https://hdl.handle.net/10371/133300 | - |
dc.description | 학위논문 (석사)-- 서울대학교 융합과학기술대학원 : 나노융합학과, 2013. 2. 이성훈. | - |
dc.description.abstract | The photoelectrode fabricated with the regular array of TiO2 nanotubes anchored with ZnS/CdSSe/CdS quantum dots was prepared by the following steps: 1) the formation of the regular array of TiO2 nanotubes on Ti metal, 2) the surface treatment of the TiO2 nanotubes with TiCl4 for the removal of surface defect sites, 3) the sequential deposition of CdS, CdSSe, and ZnS, in situ, onto the channel walls of TiO2 nanotubes by the successive ionic layer adsorption and reaction (SILAR) procedure. The tuning the band gap of CdSSe was done in terms of controlling the composition of Cd, S, or Se during the SILAR procedure. In this way, a ladder-like energy structure suitable for carrier transfer was attained from ZnS/CdSSe/CdS through TiO2 nanotubes to a Ti metal sheet. The more photoinduced charge carriers were generated and transferred from the anchored quantum dots to the TiO2 nanotubes and thus, the solar energy
conversion efficiency was enahnced. The power conversion efficiency (PCE) of our solar cell fabricated with the regular array of TiO2 nanotubes anchored with CdSSe/CdS or CdSe/CdS quantum dots was PCE = 3.49 % and 2.81 % under the illumination at 100 mW/cm2, respectively. To protect the photocorrosion of our solar cell photoanode from the electrolyte and to prevent the recombination, ZnS was introduced onto CdS/CdSSe. The power conversion efficiency (PCE) of our solar cell with the structure of a photoanode electrode, (ZnS/CdSSe/CdS/ TiO2 NTs/ a Ti metal sheet) was 4.67 % under the illumination at 100 mW/cm2. | - |
dc.description.tableofcontents | Table of Contents
Abstract……………………………………………………………………….……….………. i Table of Contents……………………………………………………………………………. iii List of Scheme……………………………………………………………………….……….. V List of Table..……………………………………………………………………….………… Vi List of Figure……………………………………………………………………….………… Vii Chapter 1 Backgrounds and Objective………………………………………………. 1 Chapter 2 Introduction………………………………………………………………….... 4 Chapter 3 Experimental 3.1 Materials…..…………………………………………………………….……………… 6 3.2 Fabrication of array of TiO2 NTs on a flat Ti sheet .……..……………….….. 6 3.3 TiCl4 Treatment on the TiO2 NTs…………….….…………………..……………. 9 3.4 SILAR procedure for the growth of CdS, CdSSe, CdSe, and ZnS layers..…......... 9 3.5 Electrolyte Solution…………………………………………………………………… 12 3.6 Characterization and Measurement of the Materials…………………………. 14 Chapter 4 Results and Discussion 4.1 Experimental Scheme………………………………………………………………… 16 4.2 Morphology of the regular array of TiO2 NTs surface-treated with TiCl4 in various concentrations…………………………………………………………… 18 4.3 Synthesis of the TiO2 NTs coupled with CdS,CdSSe……..……………………. 21 4.4 Optimal combination and sequence of QD layers on TiO2 NTs array photoelectrode for better performance.......................................................... 31 Chapter 5 Conclusions………………….……………………………………………... 35 References………………………………………………………...…………………………..... 37 Abstract (Korean)…………………………………………………………………................ 44 Acknowledgements (Korean)...................................................................................... 46 | - |
dc.format | application/pdf | - |
dc.format.extent | 1957101 bytes | - |
dc.format.medium | application/pdf | - |
dc.language.iso | en | - |
dc.publisher | 서울대학교 대학원 | - |
dc.subject | TiO2 nanotubes | - |
dc.subject | quantum dots | - |
dc.subject | SILAR | - |
dc.subject | Solar Cell | - |
dc.subject.ddc | 620 | - |
dc.title | Solar energy conversion by the regular array of TiO2 nanotubes anchored with ZnS/CdSSe/CdS quantum dots formed by sequential ionic bath deposition | - |
dc.title.alternative | TiO2나노튜브에 SILAR방법으로 ZnS/CdSSe/CdS양자점을 도입한 태양전지 연구 | - |
dc.type | Thesis | - |
dc.contributor.AlternativeAuthor | Park soojeong | - |
dc.description.degree | Master | - |
dc.citation.pages | 56 | - |
dc.contributor.affiliation | 융합과학기술대학원 나노융합학과 | - |
dc.date.awarded | 2013-02 | - |
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