Poly(3,4-dimethyl-5-vinylthiazolium)s catalyzed reactions
3,4-다이메틸-5-바이닐싸이아졸리움 고분자 촉매를 이용한 반응들
- 자연과학대학 화학부
- Issue Date
- 서울대학교 대학원
- Polymer precatalysts; Poly(vinylthiazolium)s; Thioesterification; Thiol-ene click reaction; Recycling catalyst
- 학위논문 (석사)-- 서울대학교 대학원 : 화학부 무기화학전공, 2015. 8. 정영근.
- Poly(3,4-dimethyl-5-vinylthiazolium)s were synthesized from 3,4-dimethyl-5-vinylthiazole via free radical polymerization. It examined as polymer precatalysts in the presence of DBU for the thioesterification of aldehydes with thiols and for the thiol-ene click reaction of styrene with thiols. The poly(5-vinylthiazolium)s had excellent catalytic activity and could be reused more then three times without loss of activity.