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Robust molecular-sieving graphitic membranes for gas and liquid separation : 가스 및 용매 분리를 위한 그래핀 멤브레인
DC Field | Value | Language |
---|---|---|
dc.contributor.advisor | 김용협 | - |
dc.contributor.author | 서동균 | - |
dc.date.accessioned | 2017-10-27T16:35:30Z | - |
dc.date.available | 2017-10-27T16:35:30Z | - |
dc.date.issued | 2017-08 | - |
dc.identifier.other | 000000145208 | - |
dc.identifier.uri | https://hdl.handle.net/10371/136733 | - |
dc.description | 학위논문 (박사)-- 서울대학교 대학원 공과대학 기계항공공학부, 2017. 8. 김용협. | - |
dc.description.abstract | Membrane is the most representative technology to solve the environmental crisis facing the world such as global warming, air pollution, depletion of drinking water source by water pollution.
Membrane technology means selectively separating only the desired substances from a mixed gas or solution. The principle of separation uses various principles such as physical, chemical, and mechanical. Primarily, selective separation techniques using size differences of mixed materials are used. For the recovery of wastewater produced in numerous factories or the recovery of oil spilled into the sea due to accidents, it is necessary to develop a membrane capable of selectively permeating water and oil. The situation in which water and oil are separated from each other frequently occurs and it is a necessary skill to maintain a clean environment. As the environmental pollution becomes serious, the amount of drinking water that people can drink is decreasing, and the development of new drinking water production technology is imminent due to environmental disasters such as global warming. The technology of converting seawater into freshwater, which accounts for 97% of the Earth, is an essential technology not only for the present but also for the future. Therefore, it is imperative to develop a high-performance membrane that can remove salts. In addition, the harmful gas generated from the power plant is mostly composed of CO2, and CO2 must be separated and collected in the atmosphere as a main cause of global warming. Therefore, it is urgent to develop a membrane fabrication technology capable of separating only desired gases such as CO2 from various gas molecules. It is necessary to develop high performance membrane technology with various applications. I have developed the CVHT process to improve the membrane performance. Using this process, a film can be produced due to the chemical bonding of graphene with excellent alignment. In this way, a high-performance membrane was prepared by separating the gas and the solution using a graphitic film having a very good structure. | - |
dc.description.tableofcontents | Chapter 1 Introduction 1
Chapter 2 Graphene oxide synthesis 4 2.1 Properties of graphene oxide 5 2.1.1 Graphene oxide 5 2.1.2 Mechanical property of graphene oxide 11 2.2 Hummers method 18 2.2.1 Conventional Hummers method 18 2.2.2 Modified Hummers method 21 2.3 Basic properties of GO 28 2.3.1 Morphology 28 2.3.2 Chemical structure 33 Chapter 3 Confined vapor-phase hydrothermal process 38 3.1 Conventional hydrothermal method 39 3.1.1 Graphene hydrogel 39 3.1.2 Graphene-reduction agent hydrogel 54 3.2 CVHT process 58 3.2.1 Need for graphitic film 58 3.2.2 New set-up for CVHT process 60 3.2.3 Thickness control of HGF 69 3.2.4 Mechanical property of graphitic film 75 3.2.5 Electrical property of graphitic film 82 Chapter 4 Gas separation property 86 4.1 Background of gas separation 87 4.1.1 Need for membrane 87 4.1.2 CO2/N2 and CO2/CH4 separation 91 4.2 Fabrication of graphitic membrane 94 4.2.1 Properties of graphitic film 94 4.2.2 XRD data of graphitic film 100 4.2.3 Experimental set-up 105 4.3 Gas separation performance 108 4.3.1 CO2/N2 separation 108 4.3.2 CO2/CH4 separation 116 Chapter 5 Liquid separation property 120 5.1 Background of liquid separation 121 5.1.1 Electrolyte in Li-ion battery 121 5.1.2 Water impurity in electrolyte 124 5.2 Liquid separation performance 128 5.2.1 Experimental set-up 128 5.2.2 Intrusion pressure 130 5.2.3 Separation performance of variable oils 134 5.2.4 Separation performance of electrolytes 136 Chapter 6 Conclusions 140 Bibliography 142 Abstract 151 | - |
dc.format | application/pdf | - |
dc.format.extent | 6901631 bytes | - |
dc.format.medium | application/pdf | - |
dc.language.iso | en | - |
dc.publisher | 서울대학교 대학원 | - |
dc.subject | graphene | - |
dc.subject | graphene oxide | - |
dc.subject | hydrothermal | - |
dc.subject | confined ‘vapor-phase’ hydrothermal | - |
dc.subject | gas separation | - |
dc.subject | liquid separation | - |
dc.subject.ddc | 621 | - |
dc.title | Robust molecular-sieving graphitic membranes for gas and liquid separation | - |
dc.title.alternative | 가스 및 용매 분리를 위한 그래핀 멤브레인 | - |
dc.type | Thesis | - |
dc.description.degree | Doctor | - |
dc.contributor.affiliation | 공과대학 기계항공공학부 | - |
dc.date.awarded | 2017-08 | - |
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