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Rhodium-catalyzed reactions using alcohol as a carbon monoxide, nucleophile, hydration and alkylating source : 로듐촉매를 사용하여 알코올을 일산화탄소와 친핵체, 수화 및 알킬화 공급원으로 이용하는 반응 연구
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.advisor | 정영근 | - |
| dc.contributor.author | 박하원 | - |
| dc.date.accessioned | 2017-10-31T08:35:06Z | - |
| dc.date.available | 2017-10-31T08:35:06Z | - |
| dc.date.issued | 2017-08 | - |
| dc.identifier.other | 000000144936 | - |
| dc.identifier.uri | https://hdl.handle.net/10371/138109 | - |
| dc.description | 학위논문 (석사)-- 서울대학교 대학원 자연과학대학 화학부, 2017. 8. 정영근. | - |
| dc.description.abstract | A CO-gas-free rhodium-catalyzed alkoxycarbonylation of aryl iodide with alcohols has been developed. Alcohols, with/without the aid of an aldehyde, were used as a carbon monoxide and nucleophile source.
Moreover, atom economic rhodium-catalyzed synthesis of chiral α-alkylated ketone from alkyne with benzyl alcohols has been developed. Benzyl alcohols were used as a hydration and alkylation source. | - |
| dc.description.tableofcontents | Chapter 1. Rhodium-catalyzed synthesis of esters from aryl halides using alcohols as carbon monoxide and nucleophile sources 1
1.1. Introduction 1 1.2. Results and Discussion 3 1.3. Conclusion 14 1.4. Experimental Section 15 1.5. References 31 Chapter 2. Rhodium-catalyzed synthesis of chiral α-alkylated ketone from alkyne with benzyl alcohols 34 2.1. Introduction 34 2.2. Results and Discussion 35 2.3. Conclusion 44 2.4. Experimental Section 45 2.5. References 54 국문초록 55 | - |
| dc.format | application/pdf | - |
| dc.format.extent | 1574796 bytes | - |
| dc.format.medium | application/pdf | - |
| dc.language.iso | en | - |
| dc.publisher | 서울대학교 대학원 | - |
| dc.subject | rhodium | - |
| dc.subject | ester | - |
| dc.subject | alcohol | - |
| dc.subject | alkyne | - |
| dc.subject | carbonylation | - |
| dc.subject | chiral | - |
| dc.subject | α-alkylated ketone | - |
| dc.subject | hydration | - |
| dc.subject | alkylation | - |
| dc.subject | addition reaction | - |
| dc.subject.ddc | 540 | - |
| dc.title | Rhodium-catalyzed reactions using alcohol as a carbon monoxide, nucleophile, hydration and alkylating source | - |
| dc.title.alternative | 로듐촉매를 사용하여 알코올을 일산화탄소와 친핵체, 수화 및 알킬화 공급원으로 이용하는 반응 연구 | - |
| dc.type | Thesis | - |
| dc.description.degree | Master | - |
| dc.contributor.affiliation | 자연과학대학 화학부 | - |
| dc.date.awarded | 2017-08 | - |
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