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형광화학센서를 이용한 용출기반 토양 수은 오염조사 : Determination of Mercury Ion in Contaminated Soil by Rhodamine B Hydrazide
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- Authors
- Issue Date
- 2016-06
- Publisher
- 한국지하수토양환경학회
- Citation
- 지하수토양환경, Vol.21 No.3, pp.1-5
- Abstract
- Rhodamine B Hydrazide as a novel fluorescent and colorimetric probe exhibiting remarkably selective fluorescence enhancement toward Hg2+ ion over other 16 metal ions is herein introduced. The probe reacts with Hg2+ ion followed by its spirolactam ring-opening to give a remarkable enhancement of absorption maximum at 550 nm as well as an enhanced fluorescence intensity at 580 nm in aqueous media. Upon titration with Hg2+ ion in various concentration of 10~200 uM, we found that the probe shows a marked color change from colorless to pink, enabling naked-eye detection toward mercury ion. In addition, in the presence of Hg2+ ion, the probe gave rise to change from non-florescence to strong orange fluorescence (Off-On) with a good linearity of R2=0.97. This preliminary results demonstrate that the fluorescent chemosensor we herein introduced can open a new strategy for marked selective and sensitive detection of mercury ions in contaminated soil containing various metal ions.
- ISSN
- 1598-6438
- Language
- Korean
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