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A Fluorinated Ligand Enables Room-Temperature and Regioselective Pd-Catalyzed Fluorination of Aryl Triflates and Bromides
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Sather, Aaron C. | - |
dc.contributor.author | Lee, Hong Geun | - |
dc.contributor.author | De la Rosa, Valentina Y. | - |
dc.contributor.author | Yang, Yang | - |
dc.contributor.author | Mueller, Peter | - |
dc.contributor.author | Buchwald, Stephen L. | - |
dc.creator | 이홍근 | - |
dc.date.accessioned | 2019-04-24T08:31:15Z | - |
dc.date.available | 2020-04-05T08:31:15Z | - |
dc.date.created | 2018-11-07 | - |
dc.date.created | 2018-11-07 | - |
dc.date.issued | 2015-10 | - |
dc.identifier.citation | Journal of the American Chemical Society, Vol.137 No.41, pp.13433-13438 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | https://hdl.handle.net/10371/148010 | - |
dc.description.abstract | A new biaryl monophosphine ligand (AlPhos, L1) allows for the room-temperature Pd-catalyzed fluorination of a variety of activated (hetero)aryl trifiates. Furthermore, aryl triflates and bromides that are prone to give mixtures of regioisomeric aryl fluorides with Pd-catalysis can now be converted to the desired aryl fluorides with high regioselectivity. Analysis of the solid-state structures of several Pd(II) complexes, as well as density functional theory (DFT) calculations, shed light on the origin of the enhanced reactivity observed with L1. | - |
dc.language | 영어 | - |
dc.language.iso | en | en |
dc.publisher | American Chemical Society | - |
dc.title | A Fluorinated Ligand Enables Room-Temperature and Regioselective Pd-Catalyzed Fluorination of Aryl Triflates and Bromides | - |
dc.type | Article | - |
dc.identifier.doi | 10.1021/jacs.5b09308 | - |
dc.citation.journaltitle | Journal of the American Chemical Society | - |
dc.identifier.wosid | 000363438600033 | - |
dc.identifier.scopusid | 2-s2.0-84945253747 | - |
dc.description.srnd | OAIID:RECH_ACHV_DSTSH_NO:T201720253 | - |
dc.description.srnd | RECH_ACHV_FG:RR00200001 | - |
dc.description.srnd | ADJUST_YN: | - |
dc.description.srnd | EMP_ID:A080564 | - |
dc.description.srnd | CITE_RATE:13.038 | - |
dc.description.srnd | FILENAME:4. jacs.5b09308.pdf | - |
dc.description.srnd | DEPT_NM:화학부 | - |
dc.description.srnd | EMAIL:hgleee@snu.ac.kr | - |
dc.description.srnd | SCOPUS_YN:Y | - |
dc.description.srnd | FILEURL:https://srnd.snu.ac.kr/eXrepEIR/fws/file/6153360a-df75-4437-9f40-39eb56d1a827/link | - |
dc.citation.endpage | 13438 | - |
dc.citation.number | 41 | - |
dc.citation.startpage | 13433 | - |
dc.citation.volume | 137 | - |
dc.description.isOpenAccess | Y | - |
dc.contributor.affiliatedAuthor | Lee, Hong Geun | - |
dc.identifier.srnd | T201720253 | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.subject.keywordPlus | MIYAURA COUPLING PROCESSES | - |
dc.subject.keywordPlus | F REDUCTIVE ELIMINATION | - |
dc.subject.keywordPlus | LATE-STAGE FLUORINATION | - |
dc.subject.keywordPlus | NUCLEOPHILIC FLUORINATION | - |
dc.subject.keywordPlus | AROMATIC FLUORINATION | - |
dc.subject.keywordPlus | MEDICINAL CHEMISTRY | - |
dc.subject.keywordPlus | BOND FORMATION | - |
dc.subject.keywordPlus | FLUORIDE | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | PALLADIUM | - |
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