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Effect of weakly coordinating anions on photo-stability enhancement of basic dyes in organic solvents
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Woo, Sung Wun | - |
dc.contributor.author | Kim, Jeong Yun | - |
dc.contributor.author | Hwang, Tae Gyu | - |
dc.contributor.author | Lee, Jae Moon | - |
dc.contributor.author | Kim, Hong Mo | - |
dc.contributor.author | Namgoong, JinWoong | - |
dc.contributor.author | Yuk, Sim Bum | - |
dc.contributor.author | Kim, Jae Pil | - |
dc.creator | 김재필 | - |
dc.date.accessioned | 2019-04-25T01:57:35Z | - |
dc.date.available | 2020-04-05T01:57:35Z | - |
dc.date.created | 2019-07-25 | - |
dc.date.created | 2019-07-25 | - |
dc.date.issued | 2019-01 | - |
dc.identifier.citation | Dyes and Pigments, Vol.160, pp.765-771 | - |
dc.identifier.issn | 0143-7208 | - |
dc.identifier.uri | https://hdl.handle.net/10371/150026 | - |
dc.description.abstract | Weakly coordinating anions (WCAs) offer two succinct advantages when they are introduced as counter anions in a dye. First, replacing strong electrostatic attraction between a cationic dye and its counter anion with the relatively weak electrostatic attraction from a WCA can improve photo-stability of the dye due to charge distribution. Second, the steric hindrance due to the WCAs forms a spatial obstacle between the unstable charged site of the cationic dye and an external element that may degrade the dye. In this study, WCAs are introduced as counter anions in basic dyes to improve their photostability. Basic Yellow 1, Rhodamine 6G, and Rhodamine B were selected as dyes due to their particularly low photostabilities among cationic dyes. Three WCAs were investigated, where two were composed of anions surrounded by fluorine moieties (hexafluorophosphate and bis(trifluoromethane)sulfonimide), and one is surrounded by oxygen moieties (bis(oxalate)borate) Upon dissolving these dyes in three different organic solvents (Chloroform, Methylene Chloride, and Dimethylformamide), the photostabilities of almost all the WCA-substituted dyes were comparatively improved. The photo-stability of each WCA-substituted dye was especially improved in low polarity solvents and the bis(trifluoromethane)sulfonamide-basic dye pairs showed the highest photo-stabilities among four anion-dye pairs including the unsubstituted dyes. | - |
dc.language | 영어 | - |
dc.language.iso | en | en |
dc.publisher | Elsevier BV | - |
dc.title | Effect of weakly coordinating anions on photo-stability enhancement of basic dyes in organic solvents | - |
dc.type | Article | - |
dc.identifier.doi | 10.1016/j.dyepig.2018.07.059 | - |
dc.citation.journaltitle | Dyes and Pigments | - |
dc.identifier.wosid | 000447816700093 | - |
dc.identifier.scopusid | 2-s2.0-85053422672 | - |
dc.description.srnd | OAIID:RECH_ACHV_DSTSH_NO:T201824118 | - |
dc.description.srnd | RECH_ACHV_FG:RR00200001 | - |
dc.description.srnd | ADJUST_YN: | - |
dc.description.srnd | EMP_ID:A001061 | - |
dc.description.srnd | CITE_RATE:3.767 | - |
dc.description.srnd | DEPT_NM:재료공학부 | - |
dc.description.srnd | EMAIL:jaepil@snu.ac.kr | - |
dc.description.srnd | SCOPUS_YN:Y | - |
dc.citation.endpage | 771 | - |
dc.citation.startpage | 765 | - |
dc.citation.volume | 160 | - |
dc.description.isOpenAccess | N | - |
dc.contributor.affiliatedAuthor | Kim, Jae Pil | - |
dc.identifier.srnd | T201824118 | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.subject.keywordPlus | HEPTAMETHINE CYANINE DYES | - |
dc.subject.keywordPlus | SINGLE-MOLECULE | - |
dc.subject.keywordPlus | OXYGEN | - |
dc.subject.keywordPlus | OPTIMIZATION | - |
dc.subject.keywordPlus | DEGRADATION | - |
dc.subject.keywordPlus | STABILITY | - |
dc.subject.keywordPlus | ACID | - |
dc.subject.keywordPlus | PH | - |
dc.subject.keywordAuthor | Basic dye | - |
dc.subject.keywordAuthor | Weakly coordinating anion | - |
dc.subject.keywordAuthor | WCA | - |
dc.subject.keywordAuthor | Ion pair | - |
dc.subject.keywordAuthor | Photo-stability | - |
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